Solvent dependence of the first molecular hyperpolarizability of p-nitroaniline revisited

被引：94

作者：

Woodford, JN ^{[1
]}

Pauley, MA ^{[1
]}

Wang, CH ^{[1
]}

机构：

[1] UNIV NEBRASKA,DEPT CHEM,LINCOLN,NE 68588

来源：

JOURNAL OF PHYSICAL CHEMISTRY A | 1997年 / 101卷 / 11期

关键词：

D O I：

10.1021/jp9639861

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The solvent effect on the molecular first hyperpolarizability, beta, of p-nitroaniline (pNA) has been investigated. Using the hyper-Rayleigh scattering technique, we have also determined beta of pNA in DMSO using 1064 nm laser radiation. This beta value has not been previously reported. With the help of Onsager's theory, we have arrived at a correction factor to account for the solvent dependence of the values of the intrinsic hyperpolarizability beta(0). The Onsager model significantly removes the strong solvent dependence of beta (or beta(0)) on the dielectric constant.

引用

页码：1989 / 1992

页数：4

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