Spiro-ammonium Imide Salts as Electrolytes for Lithium Batteries

被引：10
|
作者：
Abu-Lebdeh, Yaser [1 ]
Austin, Emily [1 ]
Davidson, Isobel J. [1 ]
机构：
[1] Natl Res Council Canada, Ottawa, ON K1A 0R6, Canada
来源：
CHEMISTRY LETTERS | 2009年 / 38卷 / 08期
关键词：
D O I：
10.1246/cl.2009.782
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Organic salts based on the bicyclic (spiro) ammonium cation were synthesized with a systematic variation in the size of the rings. The salts show high melting points and plastic crystal phases. The SP-56 salt showed the lowest melting point, highest ionic conductivity, and a reduction potential more positive than that of the Li/Li+ couple; therefore, it was mixed with EC before being employed in a Li/LiFePO4 battery. The battery maintained capacities between 100 and 113 mA hg(-1) over 100 cycles.
引用
收藏
页码：782 / 783
页数：2
相关论文
共 50 条
  • [1] Oligomeric bis[(perfluoroalkyl)sulfonyl]imide lithium salts as electrolytes for rechargeable lithium batteries.
    DesMarteau, DD
    Creager, SE
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2003, 226 : U524 - U524
  • [2] On the characteristics of electrolytes with new lithium imide salts
    Kita, F
    Kawakami, A
    Nie, J
    Sonoda, T
    Kobayashi, H
    [J]. JOURNAL OF POWER SOURCES, 1997, 68 (02) : 307 - 310
  • [3] On the characteristics of electrolytes with new lithium imide salts
    Kita, Fusaji
    Kawakami, Akira
    Nie, Jin
    Sonoda, Takaaki
    Kobayashi, Hiroshi
    [J]. Journal of Power Sources, 1997, 68 (2 pt 2): : 307 - 310
  • [4] Room Temperature Ionic Liquid Electrolytes Based on Azepanium Imide Salts for Lithium Batteries
    Salem, Nuha
    Nicodemou, Lucas
    Abu-Lebdeh, Yaser
    Davidson, Isobel J.
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2012, 159 (02) : A172 - A176
  • [5] Lithium-Sulfur Batteries with Micelle-Structured Electrolytes and Imide-Based Salts
    Ahmed, Faiz
    Fang, Chen
    Li, Defu
    Zhao, Yangzhi
    Liu, Gao
    [J]. ACS APPLIED ENERGY MATERIALS, 2023, 6 (13) : 7212 - 7220
  • [6] Ionic liquid and plastic crystalline phases of pyrazolium imide salts as electrolytes for rechargeable lithium-ion batteries
    Abu-Lebdeh, Y
    Abouimrane, A
    Alarco, PJ
    Armand, M
    [J]. JOURNAL OF POWER SOURCES, 2006, 154 (01) : 255 - 261
  • [7] New Lithium Salts in Electrolytes for Lithium-Ion Batteries (Review)
    Bushkova, O. V.
    Yaroslavtseva, T. V.
    Dobrovolsky, Yu. A.
    [J]. RUSSIAN JOURNAL OF ELECTROCHEMISTRY, 2017, 53 (07) : 677 - 699
  • [8] New lithium salts in electrolytes for lithium-ion batteries (Review)
    O. V. Bushkova
    T. V. Yaroslavtseva
    Yu. A. Dobrovolsky
    [J]. Russian Journal of Electrochemistry, 2017, 53 : 677 - 699
  • [9] Effects of Lithium Salts and Solvents on the Performance of Lithium-ion Batteries with Carbonate-free Electrolytes Comprising Lithium Bis(fluorosulfonyl)imide and Sulfolane
    Hirata, Kazuhisa
    Kawase, Takeo
    Sumida, Yasutaka
    [J]. CHEMISTRY LETTERS, 2020, 49 (10) : 1140 - 1143
  • [10] New and novel lithium imide electrolytes and copolymers: Synthesis and characterization for lithium rechargeable batteries.
    Venkatasetty, HV
    [J]. SIXTEENTH ANNUAL BATTERY CONFERENCE ON APPLICATIONS AND ADVANCES, 2001, : 277 - 282
12345