β-LiMoO2(AsO4)

被引:12
|
作者
Hajji, M [1 ]
Zid, MF [1 ]
Jouini, ADET [1 ]
机构
[1] Univ Tunis ElManar, Fac Sci Tunis, Lab Mat & Cristallochim, Elmanar II Tunis 2092, Tunisia
关键词
D O I
10.1107/S0108270104013162
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A new non-centrosymmetrical form of lithium molybdyl arsenate has been synthesized and grown as a single crystal. The structure of beta-LiMoO2(AsO4) is built up of corner-sharing AsO4 tetrahedra and MoO6 octahedra which form a three-dimensional framework containing tunnels running along the a axis, wherein the Li+ cations are located. This novel structure is compared with the compound LiMoO2(AsO4) of the same formula, and with those of AMO(2)(XO4) (A is Na, K, Rb or Pb, M is Mo or V, and X is P or As) and B(MoO2)(2)(XO4)(2) (B is Ba, Pb or Sr).
引用
收藏
页码:I76 / I78
页数:3
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