The enthalpies of solution of some dipeptides in aqueous urea mixtures at T=298.15 K

被引:12
|
作者
Palecz, Bartlomiej [1 ]
Belica, Sylwia [1 ]
Nowicka, Bozenna [1 ]
机构
[1] Univ Lodz, Dept Phys Chem, PL-90236 Lodz, Poland
来源
JOURNAL OF CHEMICAL THERMODYNAMICS | 2009年 / 41卷 / 08期
关键词
Aqueous solutions; Dipeptides; Urea; Dissolution enthalpy; PARTIAL MOLAR VOLUMES; ALPHA-AMINO ACIDS; SIDE-CHAIN; CONFORMATIONAL PREFERENCES; THERMODYNAMIC PROPERTIES; EXCESS-ENTHALPIES; HEAT-CAPACITIES; WATER; AMIDES; HYDROPHOBICITY;
D O I
10.1016/j.jct.2009.03.002
中图分类号
O414.1 [热力学];
学科分类号
摘要
The enthalpies of solution of glycyl-L-alpha-alanine (gly-L-ala), glycyl-L-alpha-leucine (gly-L-leu), glycyl-L-alpha-serine (gly-L-ser), and glycyl-L-alpha-aspartic acid (gly-L-asp) have been measured in water and in aqueous urea solutions with molalities from (0.25 to 3.0) mol . kg(-1) at T = 298.15 K. The experimental results were used to calculate the enthalpic coefficients of the interactions between dipeptides and urea molecules in water based on McMillan-Mayer's model. (C) 2009 Elsevier Ltd. All rights reserved.
引用
收藏
页码:923 / 925
页数:3
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