New developments in cyclic voltammetry at the dropping mercury electrode

被引：3
|
作者：
Martínez-Ortiz, F [1 ]
Alcaraz, ML [1 ]
Roca, I [1 ]
机构：
[1] Univ Murcia, Dept Quim Fis, E-30071 Murcia, Spain
来源：
ELECTROCHIMICA ACTA | 1999年 / 45卷 / 03期
关键词：
cyclic voltammetry; amalgam formation; dropping mercury electrode;
D O I：
10.1016/S0013-4686(99)00279-0
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
New theoretical and experimental results are presented for the response corresponding to a charge transfer reaction when cyclic voltammetry is applied to a dropping mercury electrode (DME). Amalgam formation for both reversible and slow electrode processes has also been considered. We show that sphericity and convective effects can be controlled experimentally so that it is easier to detect possible kinetic effects. Working curves for determining the rate constants of electrode reactions are also given. (C) 1999 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：387 / 397
页数：11
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