Synthesis of porous MoS2/CdSe/TiO2 photoanodes for photoelectrochemical water splitting

被引:49
|
作者
Wang, Yina [1 ,2 ]
Zhang, Fangfang [1 ,4 ,5 ]
Yang, Mengke [1 ,2 ]
Wang, Zheng [1 ]
Ren, Yangyang [1 ]
Cui, Jing [1 ]
Zhao, Yingao [1 ]
Du, Jimin [1 ,3 ,4 ]
Li, Kaidi [1 ,2 ]
Wang, Weimin [1 ,3 ,4 ]
Kang, Dae Joon [4 ,5 ]
机构
[1] Anyang Normal Univ, Sch Chem & Chem Engn, Anyang 455002, Henan, Peoples R China
[2] Zhengzhou Univ, Coll Chem & Mol Engn, Zhengzhou 450001, Henan, Peoples R China
[3] Henan Prov Key Lab New Optoelect Funct Mat, Anyang 455002, Henan, Peoples R China
[4] Int Joint Lab Henan Photoelect Funct Mat, Anyang 455002, Henan, Peoples R China
[5] Sungkyunkwan Univ, Dept Phys & Inst Basic Sci, 2066 Seobu Ro, Suwon 16419, Gyeonggi Do, South Korea
基金
新加坡国家研究基金会; 中国国家自然科学基金;
关键词
CdSe; MoS2; TiO2; Photocatalyst; Photoelectrochemical; Water splitting; TIO2 NANOTUBE ARRAYS; VISIBLE-LIGHT; QUANTUM DOTS; PHOTOCATALYTIC PERFORMANCE; HYDROGEN EVOLUTION; EFFICIENT; HETEROSTRUCTURES; HETEROJUNCTION; DEGRADATION; FABRICATION;
D O I
10.1016/j.micromeso.2019.04.055
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Herein, MoS2/CdSe/TiO2 ternary composites have been successfully synthesized by a simple approach. The SEM and TEM results demonstrate that MoS2/CdSe/TiO2 ternary composites have a porous structure, which can provide more active sites and mass charge transport pathways in a catalytic system. The optical measurement demonstrates that the MoS2 and CdSe coexisted in the porous TiO2 structure, which results in a wider visible light absorption than that of pure TiO2. Most importantly, the photoelectrochemical measurement results demonstrate that such ternary composite catalysts exhibit a higher photocurrent performance than that of a binary composite and pure TiO2, owing to the strong synergistic effects among MoS2, CdSe, and TiO2. These superior results show that MoS2/CdSe/TiO2 ternary composites is a promising choice for photoelectrochemical water splitting.
引用
收藏
页码:403 / 409
页数:7
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