Microwave-assisted synthesis of metal-organic framework MIL-47 for effective adsorptive removal of dibenzothiophene from model fuel

被引：21
|
作者：
Mosavi, Seyed Hossein [1 ]
Zare-Dorabei, Rouholah [1 ]
Bereyhi, Mohammad [1 ]
机构：
[1] Iran Univ Sci & Technol, Dept Chem, Res Lab Spectrometry & Micro & Nano Extract, Tehran 1684613114, Iran
来源：
JOURNAL OF THE IRANIAN CHEMICAL SOCIETY | 2021年 / 18卷 / 03期
基金：
美国国家科学基金会;
关键词：
Metal-organic frameworks; Adsorptive desulfurization; Sulfur-containing compounds; Central composite design; Microwave; EFFICIENT DESULFURIZATION; AQUEOUS-SOLUTION; DIESEL FUEL; COMPOSITE; DEEP; HYDRODESULFURIZATION; DENITROGENATION; ADSORBENT; WATER; OIL;
D O I：
10.1007/s13738-020-02057-z
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Adsorptive desulfurization performed by adsorbing dibenzothiophene from model fuels and gasoline over metal-organic framework MIL-47. The MIL-47 was synthesized by the microwave method and characterization supplied by different techniques such as scanning electron microscope, Brunauer-Emmett-Teller analysis, Fourier transform infrared, and X-ray powder diffraction analysis. For optimizing the adsorption process, central composite design was carried out in this study, and a gas chromatograph measured the concentration of dibenzothiophene. The maximum adsorption capacities (Q(0)) MIL-47 for dibenzothiophene are 1000 mg g(-1). The increment ofQ(0)is may be due to the synergistic influence of pi-complexation (betweenVand dibenzothiophene). Furthermore, reusability of MIL-47 was confirmed by regenerating it via ethanol (5 cycles) and RSD 4.53%. [GRAPHICS] .
引用
收藏
页码：709 / 717
页数：9
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