Direct synthesis of acetylene from methane by direct current pulse discharge

被引:64
|
作者
Kado, S [1 ]
Sekine, Y [1 ]
Fujimoto, K [1 ]
机构
[1] Univ Tokyo, Sch Engn, Dept Appl Chem, Bunkyo Ku, Tokyo 1138656, Japan
关键词
D O I
10.1039/a906914c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In non-catalytic direct conversion of methane to acetylene by using direct current pulse discharge under conditions of ambient temperature and atmospheric pressure, the selectivity of acetylene from methane was > 95% at methane conversion ranging from 16 to 52%; coexisting oxygen was very effective in removing deposited carbon and stabilized the state of discharge.
引用
收藏
页码:2485 / 2486
页数:2
相关论文
共 50 条
  • [1] Low temperature reforming of methane to synthesis gas with direct current pulse discharge method
    Kado, S
    Urasaki, K
    Sekine, Y
    Fujimoto, K
    [J]. CHEMICAL COMMUNICATIONS, 2001, (05) : 415 - 416
  • [2] ACETYLENE REACTION WITH HYDROGEN IN A GLOW-DISCHARGE OF DIRECT-CURRENT
    BEBESHKO, GI
    EREMIN, EN
    [J]. ZHURNAL FIZICHESKOI KHIMII, 1974, 48 (03): : 611 - 612
  • [3] Direct current cathodic glow discharge polymerization of methane and butane
    Miyama, M
    Yasuda, HK
    [J]. JOURNAL OF APPLIED POLYMER SCIENCE, 1998, 70 (02) : 237 - 245
  • [4] DIRECT SYNTHESIS FULVENE OF ACETYLENE
    CHUKHADZHYAN, GA
    ABRAMYAN, ZI
    TONYAN, GM
    [J]. ARMYANSKII KHIMICHESKII ZHURNAL, 1975, 28 (11): : 942 - 943
  • [5] Methane reforming to valuable products by an atmospheric pressure direct current discharge
    SriBala, Gorugantu
    Michiels, Dries
    Leys, Christophe
    Van Geem, Kevin M.
    Marin, Guy B.
    Nikiforov, Anton
    [J]. JOURNAL OF CLEANER PRODUCTION, 2019, 209 : 655 - 664
  • [6] Acetylene polymerization in plasma of direct current
    Alvarez, B.
    Sarmiento-Santos, A.
    Vera-Lopez, E.
    [J]. 5TH INTERNATIONAL MEETING FOR RESEARCHERS IN MATERIALS AND PLASMA TECHNOLOGY (5TH IMRMPT), 2019, 1386
  • [7] Direct Synthesis of Oxygenates from Water and Methane via Dielectric-barrier Discharge
    Bao Wei WANG
    [J]. Chinese Chemical Letters, 2004, (07) : 779 - 780
  • [8] Direct synthesis of oxygenates from water and methane via dielectric-barrier discharge
    Wang, BW
    Xu, GH
    [J]. CHINESE CHEMICAL LETTERS, 2004, 15 (07) : 779 - 780
  • [9] Polymer synthesis from 1-aminonaphthalene in direct-current discharge
    I. V. Semenov
    A. B. Gil’man
    M. Yu. Yablokov
    N. M. Surin
    A. N. Shchegolikhin
    N. A. Shmakova
    A. A. Kuznetsov
    [J]. High Energy Chemistry, 2011, 45 : 157 - 161
  • [10] Polymer Synthesis from 1-Aminonaphthalene in Direct-Current Discharge
    Semenov, I. V.
    Gil'man, A. B.
    Yablokov, M. Yu.
    Surin, N. M.
    Shchegolikhin, A. N.
    Shmakova, N. A.
    Kuznetsov, A. A.
    [J]. HIGH ENERGY CHEMISTRY, 2011, 45 (02) : 157 - 161