On the preparation of tetramethylammonium trifluoromethylbistrifluoromethylnitroxyliodate(I) (CH3)(4)N+(CF3)2NOICF(3)(-) and the reaction of tetramethylammonium bistrifluoromethylnitrate (CH3)(4)N+(CF3)(2)NO- with Cl-2 and ClONO2

被引：1

作者：

Minkwitz, R

Jakob, J

机构：

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1997年 / 623卷 / 04期

关键词：

tetramethylammonium bistrifluoromethylnitrate; tetramethylammonium trinuoromethylbistrifluoromethylnitroxyliodate(I); bistrifluoromethylnitroxyde; vibrational spectra; F-19; C-13; NMR;

D O I：

10.1002/zaac.19976230196

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The preparation of (CF3)(2)NO- as tetramethylammoniumsalt and its addition reaction with CF3I are described. The formed Tetramethylammonium trifluoromethylbistrifluoromethylnitroxyliodate(I) (CH3)(4)N+(CF3)(2)NOICF3- is characterized by its spectra and the reaction with CF3OCl. In addition we present our approach to the preparation of (CF3)(2)NOCl by the reaction of (CH3)(4)N+(CF3)(2)NO- With Cl-2 and ClONO2. The thermolabile compounds have been characterized by i. r., Raman, F-19 and C-13 NMR spectra.

引用

页码：613 / 618

页数：6

共 50 条

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