Ferroelectricity in complex chalcogenides M′M"P2X6 (M′, M" -: Sn, Pb, Cu, In, Cr; X -: S, Se)

被引：0

作者：

Vysochanskii, Y ^{[1
]}

机构：

[1] Uzhgorod State Univ, Inst Solid State Phys & Chem, UA-294000 Uzhgorod, Ukraine

来源：

FERROELECTRICS | 1998年 / 218卷 / 1-4期

关键词：

thiophosphides; selenophosphides; ferroelectric transitions; vibration spectrum;

D O I：

暂无

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

For complex thio- and selenophosphides the character of phase transitions and the vibration spectra of the crystal lattices are compared. The splitting of internal vibrations of (P2X6)(4-) anions reflects the anisotropy of crystal fields. The substitution of the chalcogen atoms in anion sublattice or the metal atoms in cation sublattice changes the mechanism of the phase transitions essentially by variation of the frustration in competing interatomic forces, in first case, and by the influence on the balance of local forces in second one.

引用

页码：629 / 636

页数：8

共 50 条

[1] Dipole ordering and critical behavior of the static and dynamic properties in three-dimensional and layered MM′P2X6 crystals (M, M′-Sn, Cu, In; X-S, Se)
Vysochanskii, YM
Molnar, AA
Stephanovich, VA
Cajipe, VB
Bourdon, X
FERROELECTRICS, 1999, 226 (1-4) : 243 - 261
[2] TERNARY METALLIC CHALCOGENIDES M3M'2X2 (M=NI, CO, PD, RH), (M'=IN, TL, SN, PB, BI), (X=S, SE) WITH SHANDITE AND PARKERITE STRUCTURE
ZABEL, M
WANDINGER, S
RANGE, KJ
ZEITSCHRIFT FUR KRISTALLOGRAPHIE, 1979, 149 (1-2): : 157 - 157
[3] STOICHIOMETRY AND PHYSICAL-PROPERTIES OF TERNARY MOLYBDENUM CHALCOGENIDES MXMO6X8 (X = S, SE, M = LI, SN, PB)
TARASCON, JM
DISALVO, FJ
MURPHY, DW
HULL, GW
RIETMAN, EA
WASZCZAK, JV
JOURNAL OF SOLID STATE CHEMISTRY, 1984, 54 (02) : 204 - 212
[4] THE PHASE-DIAGRAMS OF M(2)X-SIX(2) (M IS CU, AG, X IS S, SE)
VENKATRAMAN, M
BLACHNIK, R
SCHLIEPER, A
THERMOCHIMICA ACTA, 1995, 249 : 13 - 20
[5] Misfit layer compounds (MX)(1+x)(TX(2))(m) M=Pb, Bi, Sn; T=Ti, v, Cr, Ta, Nb; X=S, Se; 0.08<x<0.28; m=1, 2, 3
Rouxel, J
Meerschaut, A
PHYSICS AND CHEMISTRY OF LOW-DIMENSIONAL INORGANIC CONDUCTORS, 1996, 354 : 59 - 70
[6] EMBEDDINGS OF SN X M IN SN+2 X M FORM A GROUP
OCKEN, S
ILLINOIS JOURNAL OF MATHEMATICS, 1982, 26 (02) : 236 - 251
[7] BIS(BIDENTATE) COMPLEXES OF IMINOBIS(DIPHENYLPHOSPHINE CHALCOGENIDES) [M(N(XPPH(2))(2)-X,X')(2)] (X=S OR SE M=NI, PD OR PT)
BHATTACHARYYA, P
NOVOSAD, J
PHILLIPS, J
SLAWIN, AMZ
WILLIAMS, DJ
WOOLLINS, JD
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1995, (10): : 1607 - 1613
[8] The Solid Solutions M19Q6X7 with M = Ag, Cu; Q = S, Se, Te and X = S, Se, Te
Nilges, Tom
Messel, Julia
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2008, 634 (12-13): : 2185 - 2190
[9] New ternary uranium chalcogenides M(2)U(6)X(15.5)(M=Rh,Ir and X=S,Se): Synthesis, crystal structure and magnetic properties
Daoudi, A
Noel, H
JOURNAL OF ALLOYS AND COMPOUNDS, 1996, 233 (1-2) : 169 - 173
[10] First-principles study on the electronic and optical properties of 2D chalcogenides M2X and M2X3 (M = Tl, in and X = O, S, Se)
Li, Huanhuan
Hu, Songhua
Zhao, Shuai
Lan, Chunfeng
CHEMICAL PHYSICS LETTERS, 2020, 749

← 1 2 3 4 5 →