Small Size Rh Nanoparticles in Micelle Nanostructure by Ionic Liquid/CTAB for Acceptorless Dehydrogenation of Alcohols Only in Pure Water

被引：15

作者：

Yao, Lin ^{[1
]}

Zhao, Jun ^{[1
]}

Lee, Jong-Min ^{[1
]}

机构：

[1] Nanyang Technol Univ, Sch Chem & Biomed Engn, 62 Nanyang Dr, Singapore 637459, Singapore

来源：

ACS SUSTAINABLE CHEMISTRY & ENGINEERING | 2017年 / 5卷 / 03期

关键词：

Ionic liquid; Rhodium; Catalyst; Nanoparticle; Water; OPPENAUER-TYPE OXIDATION; OXIDANT-FREE DEHYDROGENATION; AQUEOUS HYDROGEN-PEROXIDE; SECONDARY ALCOHOLS; BENZYL ALCOHOL; COMPLEXES; CATALYST; LIGAND; PHASE; NANOCLUSTERS;

D O I：

10.1021/acssuschemeng.6b02994

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Ultrasmall size Rh nanoparticles were synthesized and stabilized by the complex of cetyltrimethylammonium bromide and water-soluble ionic liquid molecules. The new catalytic system shows excellent catalytic activity in the oxidation of alcohols to aldehydes or ketones only in pure water through acceptorless dehydrogenation. It is atom economic, clean and green in the synthesis of aldehydes or ketones and H-2 production at the same time.

引用

页码：2056 / 2060

页数：5