Dipotassium trimanganese(II) tetrakis(hydrogenphosphite), K2[Mn3(HPO3)4]

被引：7

作者：

Hamchaoui, Farida ^{[1
,2
]}

Alonzo, Veronique ^{[2
]}

Roisnel, Thierry ^{[3
]}

Rebbah, Houria ^{[1
]}

Le Fur, Eric ^{[2
]}

机构：

[1] Univ Sci & Technol Houari Boumediene, Fac Chim, Mat Sci Lab, Bab Ezzouar 16111, Alger, Algeria

[2] CNRS, Ecole Natl Super Chim Rennes, UMR 6226, F-35708 Rennes 7, France

[3] Univ Rennes 1, CNRS, CDIFX, UMR 6226, F-35042 Rennes, France

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 2009年 / 65卷

关键词：

HYDROTHERMAL SYNTHESIS; CRYSTAL-STRUCTURE; MAGNETIC-PROPERTIES; MANGANESE(II) PHOSPHITE;

D O I：

10.1107/S010827010901957X

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The title compound is a new mixed alkali/3d metal phosphite. It exhibits a layered structure formed by linear Mn3O12 trimer units which contain face-sharing MnO6 octahedra interconnected by (HPO3)(2-) phosphite oxoanions. The K+ cations located between the anionic [Mn-3(HPO3)(4)](2-) sheets are ninefold coordinated. The presence of the alkaline ion leads to the highest symmetry and shortest interlayer distance compared with two previous compounds showing the same anionic framework and having ammonium salts as cations. The compound crystallizes in the space group R (3) over barm, with two crystallographically independent Mn atoms occupying sites of (3) over barm and 3m symmetry. All the other atoms, except for the phosphite O atoms, are located on special positions with 3m symmetry.

引用

页码：I33 / I35

页数：3

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