Isomerization of matrix-isolated formamide: IR-spectroscopic detection of formimidic acid

被引：0
|
作者：
Maier, G [1 ]
Endres, J [1 ]
机构：
[1] Univ Giessen, Inst Organ Chem, D-35392 Giessen, Germany
来源：
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2000年 / 2000卷 / 06期
关键词：
photochemistry; matrix isolation; density functional calculations; isomerization;
D O I：
暂无
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Ultraviolet irradiation of matrix-isolated formamide (1) in solid argon with light of wavelength 248 nm leads to the formation of formimidic acid (2). Comparison of the experimental IR spectrum of the photoproduct with the calculated IR spectrum of 2 shows clearly that two rotamers 2a and 2b are formed.
引用
收藏
页码：1061 / 1063
页数：3
相关论文
共 50 条
  • [1] IR-SPECTROSCOPIC STUDY OF THE STRUCTURES OF MATRIX-ISOLATED COMPLEXES OF AMINES WITH HCL AND DC1
    LEBEDEVA, TL
    [J]. BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE, 1981, 30 (05): : 719 - 723
  • [2] IR SPECTROSCOPIC EVIDENCE FOR MATRIX-ISOLATED SF6-
    BAREFIELD, JE
    GUILLORY, WA
    [J]. JOURNAL OF PHYSICAL CHEMISTRY, 1977, 81 (07): : 634 - 636
  • [3] SPECTROSCOPIC OBSERVATION OF MATRIX-ISOLATED SILATOLUENE
    KREIL, CL
    CHAPMAN, OL
    BURNS, GT
    BARTON, TJ
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1980, 102 (02) : 841 - 842
  • [4] SPECTROSCOPIC SEARCH FOR MATRIX-ISOLATED ACETYLNITRENE
    FERRANTE, RF
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1990, 200 : 145 - PHYS
  • [5] Photochemistry of matrix-isolated 4-diazo-4H-imidazole:: IR-spectroscopic identification of 4H-imidazol-4-ylidene
    Maier, G
    Endres, J
    [J]. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2000, 2000 (14) : 2535 - 2539
  • [6] CHARACTERIZATION OF MATRIX-ISOLATED CU(CO)CL - IR SPECTROSCOPIC INVESTIGATION AND ABINITIO CALCULATION
    PLITT, HS
    BAR, MR
    AHLRICHS, R
    SCHNOCKEL, H
    [J]. INORGANIC CHEMISTRY, 1992, 31 (03) : 463 - 465
  • [7] SEARCH FOR IR FUNDAMENTAL OF MATRIX-ISOLATED XEF
    AULT, BS
    ANDREWS, L
    GREEN, DW
    REEDY, GT
    [J]. JOURNAL OF CHEMICAL PHYSICS, 1977, 66 (07): : 2786 - 2788
  • [8] UV-INDUCED ISOMERIZATION OF (E)-CROTONIC ACID - COMBINED MATRIX-ISOLATED IR AND AB-INITIO MO STUDY
    FAUSTO, R
    KULBIDA, A
    SCHREMS, O
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1995, 91 (21): : 3755 - 3770
  • [9] Spectroscopic characterization of matrix-isolated phenylcarbene and cycloheptatetraene
    Matzinger, S
    Bally, T
    [J]. JOURNAL OF PHYSICAL CHEMISTRY A, 2000, 104 (16): : 3544 - 3552
  • [10] SPECTROSCOPIC STUDIES ON MATRIX-ISOLATED MOLYBDENUM PENTACHLORIDE
    BRISDON, AK
    GRAHAM, JT
    HOPE, EG
    JENKINS, DM
    LEVASON, W
    OGDEN, JS
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1990, (05): : 1529 - 1532
12345