Coercivity enhancement in Mn-Al-Cu flakes produced by surfactant-assisted milling

被引:21
|
作者
Saravanan, P. [1 ]
Hsu, Jen-Hwa [2 ]
Vinod, V. T. P. [3 ]
Cernik, Miroslav [3 ]
Kamat, S. V. [1 ]
机构
[1] Def Met Res Lab, Hyderabad 500058, Andhra Pradesh, India
[2] Natl Taiwan Univ, Dept Phys, Taipei 106, Taiwan
[3] Tech Univ Liberec, Dept Nat Sci, Inst Nanomat Adv Technol & Innovat, Liberec 46117 1, Czech Republic
关键词
MAGNETIC-PROPERTIES; PERMANENT-MAGNETS; SINGLE-CRYSTAL; SUBMICRON; MECHANISM;
D O I
10.1063/1.4935861
中图分类号
O59 [应用物理学];
学科分类号
摘要
We herein report the achievement of exceptionally high coercivity (H-c) values: 9.92 and 5.86 kOe at 5 and 300 K, respectively, for Mn55Al43Cu2 flakes produced by surfactant-assisted milling process without employing any heat-treatment. The use of surfactants such as oleic acid and oleylamine during milling yielded high-aspect ratio flakes for the Mn-Al-Cu alloy. Structural studies confirmed the presence of tau- and beta-phases as the major constituents in the Mn-Al-Cu flakes. The observed H-c enhancement is due to the increase in anisotropy field and structural defects, which is hypothesized to originate from the domain-wall pinning as a consequence of precipitation of fine Cu-particles present at the grain boundaries. (C) 2015 AIP Publishing LLC.
引用
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页数:5
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