Highly selective hydrogenation of furfural to furan-2-ylmethanol over a Cu/C derived from copper-organic frameworks

被引：7

作者：

Li, Zhi-Xin ^{[1
]}

Wei, Xian-Yong ^{[1
,2
]}

Yang, Zheng ^{[1
]}

Zhang, Min ^{[1
]}

Niu, Shuo ^{[1
]}

Meng, Xing-Long ^{[1
]}

Li, Jun ^{[1
]}

Zong, Zhi-Min ^{[1
]}

机构：

[1] China Univ Min & Technol, Key Lab Coal Proc & Efficient Utilizat, Minist Educ, Xuzhou 221116, Jiangsu, Peoples R China

[2] Ningxia Univ, State Key Lab High Efficiency Coal Utilizat & Gre, Yinchuan 750021, Ningxia, Peoples R China

来源：

CATALYSIS COMMUNICATIONS | 2019年 / 129卷

关键词：

Furfural; Selective hydrogenation; Furan-2-ylmethanol; Metal-organic frameworks; Cu/C; PHASE HYDROGENATION; PROMISING PLATFORM; CATALYSTS; EFFICIENT; ALCOHOL; NANOPARTICLES; CONVERSION; BIOMASS;

D O I：

10.1016/j.catcom.2019.04.011

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Highly selective hydrogenation of furfural to furan-2-ylmethanol (FM) was developed over a Cu/C derived from copper-organic frameworks at 500 degrees C. It was found that the calcination temperature of copper-organic frameworks greatly affected the properties of Cu/C. Under optimal conditions, furfural conversion (FC) and FM selectivity (FMS) are 99.4% and 100%, respectively. Interestingly, the hydrogenation of furfural to FM could also proceed in weakly polar solvents. The activity and selectivity of Cu/C are still at a high level (92.6% FC and 100% FMS) even after 6-times recycle.

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页数：3

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