Five- and six-coordinate 2-methyl-2-propanethiolato complexes of zirconium(IV): Synthesis and structures of [Li(DME)(3)][Zr(SCMe(3))(5)] and [(THF)Li]Zr-2(SCMe(3))(6)

被引：14

作者：

Kawaguchi, H

Tatsumi, K

Cramer, RE

机构：

[1] UNIV HAWAII,HONOLULU,HI 96822

[2] NAGOYA UNIV,FAC SCI,DEPT CHEM,CHIKUSA KU,NAGOYA,AICHI 46401,JAPAN

来源：

INORGANIC CHEMISTRY | 1996年 / 35卷 / 15期

关键词：

D O I：

10.1021/ic951211l

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Five-coordinate and six-coordinate 2-methyl-2-propanethiolato complexes of zirconium, [Li(DME)(3)][Zr(SCMe(3))(5)] (1) and [(THF)Li]Zr-2(SCMe(3))(6) (2), were obtained from the ZrCl4/LiSCMe(3) reaction system. The control of the Zr coordination number, by the ether ligands, THF or DME, bound to Li, is demonstrated by the conversion of 2 into 1 upon dissolution in DME. 1 and 2 were crystallographically characterized. The structures are extensively disordered. Crystal data follow: 1, hexagonal P6(3)/m, a = b = 12.496(3) Angstrom, c = 17.561(9) Angstrom, Z = 2, V = 2375(1) Angstrom(3), R = 5.0%, R(w) = 6.8%; 2, trigonal R32, a = b = 11.813(3) Angstrom c = 28.37(1) Angstrom, Z = 3, V = 3428(1) Angstrom(3), R = 5.2%, R(w) = 6.4%.

引用

页码：4391 / 4395

页数：5

共 50 条

[1] Synthesis and crystal structures of zirconium(IV) nitrate complexes (NO2)[Zr(NO3)3(H2O)3]2(NO3)3, Cs[Zr(NO3)5] and (NH4)[Zr(NO3)5](HNO3)
Morozov, IV
Fedorova, AA
Palamarchuk, DV
Troyanov, SI
[J]. RUSSIAN CHEMICAL BULLETIN, 2005, 54 (01) : 93 - 98
[2] Synthesis and crystal structures of zirconium(IV) nitrate complexes (NO2)[Zr(NO3)3(H2O)3]2(NO3) 3, Cs[Zr(NO3)5], and (NH4)[Zr(NO3)5](HNO3)
I. V. Morozov
A. A. Fedorova
D. V. Palamarchuk
S. I. Troyanov
[J]. Russian Chemical Bulletin, 2005, 54 : 93 - 98
[3] ISOLATION OF LITHIUM HEXAMETHYLZIRCONATE(IV), LI2(ZR(CH3)6)
BERTHOLD, HJ
GROH, G
[J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1970, 372 (03): : 292 - &
[4] 5 COORDINATE ZIRCONIUM(IV) COMPLEXES WITH THE (ETA-C5H5)2ZRIV UNIT - THE STRUCTURE OF (ETA-C5H5)2ZR(CF3SO3)2(THF)
THEWALT, U
LASSER, W
[J]. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1983, 38 (11): : 1501 - 1505
[5] Five- and six-coordinate ruthenium complexes with the tridentate orthometallated aryl bisphosphine ligand [2,6-(Ph2PCH2)(2)C6H3](-)
Jia, GC
Lee, HM
Williams, LD
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1997, 534 (1-2) : 173 - 180
[6] Syntheses and crystal structures of new amido- and imidobridged cobalt clusters:: [Li(THF)2]3[Co3(μ2-NHMes)3Cl6] (1), [Li(DME)3]2[Co18(μ4-NPh)3(μ3-NPh)12Cl3] (2), [Li(DME)3]2[Co6(μ4-NPh)(μ2-NPh)6(PPh2Et)2] (3), and [Li(THF)4][Co8(μ3-NPh)6(μ2-NPh)3(PPh3)2] (4)
Link, H
Fenske, D
[J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1999, 625 (11): : 1878 - 1884
[7] Synthesis, characterization, antifungal properties and X-ray crystal structures of five- and six-coordinate copper(II) complexes of the 6-methyl-2-formylpyridine4N-dimethylthiosemicarbazone
Ali, MA
Mirza, AH
Hossain, AMS
Nazimuddin, M
[J]. POLYHEDRON, 2001, 20 (9-10) : 1045 - 1052
[8] An unusual trimeric bimetallic Li-Zr complex with the backbone [Zr-3(mu(2)-OH)(3)(mu(3)-O)Li-5] by reaction of zirconiumorgano and hydrido complexes with water
Walther, D
Ritter, B
Gorls, H
Zahn, G
[J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1997, 623 (07): : 1125 - 1130
[9] SYNTHESIS AND X-RAY CRYSTAL-STRUCTURES OF THE MONONUCLEAR AND BINUCLEAR ARYLMANGANATE COMPLEXES [(LI(ET2O)2)2MN2PH6], [LI(THF)4]2[MN2PH6], AND [LI(THF)4][MNMES3]
BARTLETT, RA
OLMSTEAD, MM
POWER, PP
SHONER, SC
[J]. ORGANOMETALLICS, 1988, 7 (08) : 1801 - 1806
[10] Zirconium indenylamido complexes:: synthesis and reactivity -: Crystal structure of [Zr(Ind)2(NC3H6)2]
Ascenso, JR
de Azevedo, CG
Correia, MJ
Dias, AR
Duarte, MT
da Silva, JLF
Gomes, PT
Lourenço, F
Martins, AM
Rodrigues, SS
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2001, 632 (1-2) : 58 - 66

← 1 2 3 4 5 →