Vibrational study of (CH3)4NSbCl6 and [(CH3)4N]2SiF6

(CH3)(4)NSbCl6 and [(CH3)(4)N](2)SiF6 are face-centred cubic compounds at ambient temperature with a = 11.548 and 11.172 Angstrom, respectively. The vibrational spectra of these two compounds are discussed in relation to their crystal structure and other compounds containing (CH3)(4)N+ ions. The assignment of the observed bands is discussed. The Raman and infrared spectra of [(CH3)(4)N](2)SiF6 show that the cations and anions are not distorted inside the crystals and are weakly hydrogen-bonded to each other. The infrared spectrum of (CH3)(4)NSbCl6 confirms a cubic structure for this compound at ambient temperature, in which cations are in octahedral environments and can be interpreted as being disordered groups. No evidence could be found for the existence of hydrogen bonding between cations and anions in this compound. The phase transition of (CH3)(4)NSbCl6 is studied by means of Raman spectroscopy. It is believed to be governed by the reorientational motions of tetramethylammonium cations and may be classified as an 'order-disorder' type. (C) 2002 Elsevier Science B.V. All rights reserved.