Copolymerization of styrene and vinyl acetate by successive photoinduced charge-transfer polymerization

被引：0

作者：

Huang, XY ^{[1
]}

Huang, ZH ^{[1
]}

Huang, JL ^{[1
]}

机构：

[1] Fudan Univ, Dept Macromol Sci, Open Lab Mol Engn Polymers, Educ Minist China, Shanghai 200433, Peoples R China

来源：

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 2000年 / 38卷 / 05期

关键词：

block copolymerization; styrene; vinyl acetate; charge-transfer polymerization; hydrolysis;

D O I：

10.1002/(SICI)1099-0518(20000301)38:5<914::AID-POLA16>3.0.CO;2-K

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The synthesis of a diblock copolymer of styrene and vinyl acetate (VAC), PS-b-PVAC, was performed by successive photoinduced charge-transfer polymerization (CTP) under UV irradiation. A novel amphiphilic diblock copolymer of PS-b-PVA then was obtained by the hydrolysis of the diblock copolymer PS-b-PVAC with sodium ethoxide as a catalyst. Both of them were characterized by Fourier transform infrared, H-1 NMR, and gel permeation chromatography in detail. The effect of the solvents on the CTP and the kinetics of the CTP are discussed. (C) 2000 John Wiley & Sons, Inc.

引用

页码：914 / 920

页数：7

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