Growth of zinc hexacyanoferrate nanocubes and their potential as heterogeneous catalyst for solvent-free oxidation of benzyl alcohol

被引：46
|
作者：
Ali, S. R. [1 ]
Bansal, V. K. [2 ]
Khan, A. A. [2 ]
Jain, S. K. [3 ]
Ansari, M. A. [4 ]
机构：
[1] Govt PG Coll, Dept Chem, Narayan Nagar 262550, Uttarakhand, India
[2] Indian Inst Technol, Dept Chem, Roorkee 247667, Uttar Pradesh, India
[3] Gurukula Kangri Univ, Dept Chem, Haridwar 249404, Uttarakhand, India
[4] Bipin Bilian PG Sci Coll, Dept Chem, Jhansi 284001, Uttar Pradesh, India
来源：
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 2009年 / 303卷 / 1-2期
关键词：
Metal hexacyanoferrates; Zinc hexacyanoferrate nanocube; Oxidation of benzyl alcohol; Benzaldehyde; AMPEROMETRIC DETERMINATION; ELECTROCATALYTIC OXIDATION; COMPLEXES; ADSORPTION; NANOPARTICLES; ELECTRODE; RIBONUCLEOTIDES; NUCLEOTIDES; FABRICATION; RELEVANCE;
D O I：
10.1016/j.molcata.2008.12.020
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Zinc hexacyanoferrate nanocubes have been synthesized following an extremely simple method and characterized by elemental analysis, thermal analysis, infrared spectroscopic and X-ray diffraction techniques. Field emission scanning electron microscopic image showed that it consisted of sharp Cubic particles With size ranging from 83 to 164 nm. Catalytic activity of nanocubic Zinc hexacyanoferrate has been studied for solvent-free oxidation of benzyl alcohol using H2O2 as oxidant under the optimum conditions of certain parameters such as benzyl alcohol to H2O2 molar ratio, the amount of catalyst, reaction time and temperature. (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码：60 / 64
页数：5
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