Dimerization and oligomerization of ethylene catalyzed by a palladium(II) complex with imine-phosphine ligand

被引:13
|
作者
Chen, JT [1 ]
Liu, ST [1 ]
Zhao, KQ [1 ]
机构
[1] Natl Taiwan Univ, Dept Chem, Taipei 106, Taiwan
关键词
ethylene; dimerization; palladium; iminephosphine;
D O I
10.1002/jccs.200000035
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The palladium-iminophosphine complex [Pd(P-N)(CH3)Cl] (P-N = o-diphenyl-phosphino-N-benzaldimine) has been found to be a catalyst for dimerization and trimerization of ethylene. Some mechanistic insight concerning this oligomerization is discussed.
引用
收藏
页码:279 / 281
页数:3
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