Synthesis, Crystal Structures, and Magnetic Properties of Two FeIII-DyIII Coordination Clusters with N,N,N',N'-Tetrakis(2-hydroxyethyl)ethylenediamine (edteH4) as Ligand

被引：0

作者：

Chen, Sihuai ^{[1
]}

Jia, Lihui ^{[1
]}

机构：

[1] Wuhan Inst Technol, Sch Chem & Environm Engn, Key Lab Green Chem Proc, Minist Educ, Wuhan 430073, Peoples R China

来源：

RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2022年 / 67卷 / SUPPL 1期

基金：

中国国家自然科学基金;

关键词：

N; N'; N'-tetrakis(2-hydroxyethyl)ethylenediamine; 3d-4f complex; magnetic properties; single-molecule magnets; SINGLE-MOLECULE MAGNET; HIGH-SPIN MOLECULES; COMPLEX-COMPOUNDS; SUSCEPTIBILITY; ANISOTROPY; IRON(II); LN;

D O I：

10.1134/S0036023622601519

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two Fe-III-Dy-III coordination clusters, namely [Fe4Dy2(mu(4)-O)(2)(Hedte)(2)(m-CH3C6H4COO)(4.6)(NO3)(3.4)] (1) and [Fe4Dy2(mu(4)-O)(2)(Hedte)(2)(m-NO2C6H4COO)(4) (NO3)(4)]center dot 0.5MeCN (2), have been synthesized using N,N,N',N'-tetrakis(2-hydroxyethyl)ethylenediamine (edteH(4)) as ligand. Both compounds possess identical {Fe4Dy2} central cores and the magnetic susceptibility measurements indicate the presence of ferromagnetic interactions in both compounds. However, the AC susceptibility measurements only show weak out-of-phase AC signals for compound 2.

引用

页码：S22 / S28

页数：7

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