Model of carbon corrosion in PEM fuel cells

被引：341
|
作者：
Meyers, JP [1 ]
Darling, RM [1 ]
机构：
[1] UTC Fuel Cells, S Windsor, CT 06074 USA
来源：
JOURNAL OF THE ELECTROCHEMICAL SOCIETY | 2006年 / 153卷 / 08期
关键词：
D O I：
10.1149/1.2203811
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
This paper presents a mathematical model of the corrosion of carbon catalyst supports in polymer electrolyte membrane (PEM) fuel cells. The model describes how a maldistribution of hydrogen across the fuel electrode can induce both oxygen evolution and carbon corrosion on the positive electrode of the fuel cell in the fuel-starved region. Implications of this reverse-current mechanism are explored by simulating a cell with a nonuniform distribution of hydrogen along the fuel channel in both steady-state and transient operation. (c) 2006 The Electrochemical Society.
引用
收藏
页码：A1432 / A1442
页数：11
相关论文
共 50 条
  • [1] CFD Study of Carbon Corrosion in PEM Fuel Cells
    Gidwani, Ashok
    Jain, Kunal
    Kumar, Sanjiv
    Cole, J. Vernon
    [J]. PROTON EXCHANGE MEMBRANE FUEL CELLS 8, PTS 1 AND 2, 2008, 16 (02): : 1323 - +
  • [2] A Simple Model for Carbon Corrosion in PEM Fuel Cell
    Kulikovsky, A. A.
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2011, 158 (08) : B957 - B962
  • [3] A Semi-Empirical Two Step Carbon Corrosion Reaction Model in PEM Fuel Cells
    Young, A. P.
    Colbow, V.
    Harvey, D.
    Rogers, E.
    Wessel, S.
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2013, 160 (04) : F381 - F388
  • [4] Corrosion Study of Mesoporous Carbon Supports for Use in PEM Fuel Cells
    Forouzandeh, Farisa
    Banham, Dustin W.
    Feng, Fangxia
    Li, Xiaoan
    Ye, Siyu
    Birss, Viola
    [J]. POLYMER ELECTROLYTE FUEL CELLS 13 (PEFC 13), 2013, 58 (01): : 1739 - 1749
  • [5] Carbon Corrosion in PEM Fuel Cells and the Development of Accelerated Stress Tests
    Macauley, Natalia
    Papadias, Dennis D.
    Fairweather, Joseph
    Spernjak, Dusan
    Langlois, David
    Ahluwalia, Rajesh
    More, Karren L.
    Mukundan, Rangachary
    Borup, Rodney L.
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2018, 165 (06) : F3148 - F3160
  • [6] Computational fluid dynamics modeling of carbon corrosion in PEM fuel cells
    Gidwani, Ashok
    Jain, Kunal
    Thoms, Richard
    Cole, James Vernon
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2009, 238
  • [7] Corrosion of carbon support for PEM fuel cells by electrochemical quartz crystal microbalance
    Hung, Chih-Cheng
    Lim, Pau-Yee
    Chen, Jiann-Ruey
    Shih, Han C.
    [J]. JOURNAL OF POWER SOURCES, 2011, 196 (01) : 140 - 146
  • [8] FUEL 77-Mitigation of cathode carbon corrosion using sacrificial carbon layer in PEM fuel cells
    Zhang, Jingxin
    Owejan, Jeanette
    Fay, Matthew
    Litteer, Brian A.
    Yu, Paul T.
    Gu, Wenbin
    Gasteiger, Hubert A.
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2007, 234
  • [9] Characterization of Carbon Corrosion in a Segmented PEM Fuel Cell
    Spernjak, Dusan
    Fairweather, Joseph
    Rockward, Tommy
    Mukundan, Rangachary
    Borup, Rodney L.
    [J]. POLYMER ELECTROLYTE FUEL CELLS 11, 2011, 41 (01): : 741 - 750
  • [10] Non-kinetic losses caused by electrochemical carbon corrosion in PEM fuel cells
    Park, Sehkyu
    Shao, Yuyan
    Viswanathan, Vilayanur V.
    Liu, Jun
    Wang, Yong
    [J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2012, 37 (10) : 8451 - 8458
12345