Michael Addition Reaction of Malononitrile and α,β-Unsaturated Ketones Catalyzed by Amine Functionalized MCM-41

被引：5

作者：

Wang, Changchun

Xie, Shaolei

Xie, Zhengfeng

Hui, Yonghai ^{[1
]}

机构：

[1] Xinjiang Univ, Key Lab Oil & Gas Fine Chem, Minist Educ, Urumqi 830046, Peoples R China

来源：

CHINESE JOURNAL OF ORGANIC CHEMISTRY | 2013年 / 33卷 / 11期

基金：

中国国家自然科学基金;

关键词：

amine functionalized MCM-41; alpha; beta-unsaturated ketones; malononitrile; catalysis; Michael addition; KNOEVENAGEL CONDENSATION; CONJUGATE ADDITIONS; EFFICIENT;

D O I：

10.6023/cjoc201305016

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Michael addition reaction of alpha,beta-unsaturated ketones and malononitrile that catalyzed by amine functionalized MCM-41 in methanol afforded a series of cyano derivatives with high yield (up to 99%). The products were afforded at room temperature. Moreover, the catalyst was also found to easiness to handle up, friendly environment, and excellent recyclability.

引用

页码：2391 / 2395

页数：5

共 28 条

[1] Alessio R., 2009, ADV SYNTH CATAL, V351, P3067
[2] [Anonymous], 2003, ANGEW CHEM INT ED, DOI DOI 10.1021/OL050431S
[3] Conjugate additions of nitroalkanes to electron-poor alkenes: Recent results
Ballini, R
Bosica, G
Fiorini, D
Palmieri, A
Petrini, M
[J]. CHEMICAL REVIEWS, 2005, 105 (03) : 933 - 971
[4] Bergman E., 1959, ORG REACT, V10, P179, DOI DOI 10.1002/0471264180.OR010.03
[5] Mesoporous SBA-15 with Short Mesochannels Immobilized Natural Quinine for Asymmetric Michael Addition of Chalcones
Chen, Qiu
Xin, Cui
Lou, Lan-Lan
Yu, Kai
Ding, Fei
Liu, Shuangxi
[J]. CATALYSIS LETTERS, 2011, 141 (09) : 1378 - 1383
[6] Efficient asymmetric transfer hydrogenation of activated olefins catalyzed by ruthenium amido complexes
Chen, YC
Xue, D
Deng, JG
Cui, X
Zhu, J
Jiang, YZ
[J]. TETRAHEDRON LETTERS, 2004, 45 (07) : 1555 - 1558
[7] Friedel-Crafts Reaction of Indoles with Nitroalkenes Catalyzed by Mesoporous Material MCM-41
Chen, Yongcheng
Xie, Shaolei
Xie, Zhengfeng
[J]. CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2012, 32 (10) : 1970 - 1974
[8] Schiff base supported MCM-41 catalyzed the Knoevenagel condensation in water
Dong, Xiuzhi
Hui, Yonghai
Xie, Shaolei
Zhang, Peng
Zhou, Guangpeng
Xie, Zhengfeng
[J]. RSC ADVANCES, 2013, 3 (10): : 3222 - 3226
[9] Catalytic asymmetric conjugate addition of nitroalkanes to cycloalkenones
Hanessian, S
Pham, V
[J]. ORGANIC LETTERS, 2000, 2 (19) : 2975 - 2978
[10] MCM-41-Supported Bidentate Phosphine Rhodium Complex: An Efficient and Recyclable Heterogeneous Catalyst for the Hydrosilylation of Olefins
Hu Ronghua
Hao Wenyan
Cai Mingzhong
[J]. CHINESE JOURNAL OF CHEMISTRY, 2011, 29 (08) : 1629 - 1634

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