Enantioselective total synthesis of valeriananoids A-C

被引：22
|
作者：
Srikrishna, A [1 ]
Satyanarayana, G [1 ]
机构：
[1] Indian Inst Sci, Dept Organ Chem, Bangalore 560012, Karnataka, India
来源：
ORGANIC LETTERS | 2004年 / 6卷 / 14期
关键词：
D O I：
10.1021/ol049341y
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The first enantioselective total synthesis of valeriananoids A-C (-)-1-3 is reported starting from the readily available monoterpene (R)-carvone, employing a tandem intermolecular Michael addition-intramolecular Michael addition-alkylation sequence and an electron-transfer-mediated 6-endo-trig cyclization as key steps.
引用
收藏
页码：2337 / 2339
页数：3
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