Composition and temperature dependence of ferroelectric and pyroelectric properties of (1-x)[PMN-PT(65/35)]-xPZ (0 ≤ x ≤ 0.10) ceramics

被引：4
|
作者：
Jiang, Tong [1 ]
Li, Qiang [1 ]
Yan, Qingfeng [1 ]
Luo, Nengneng [1 ]
Zhang, Yiling [2 ]
Chu, Xiangcheng [2 ]
机构：
[1] Tsinghua Univ, Dept Chem, Beijing 10084, Peoples R China
[2] Tsinghua Univ, State Key Lab New Ceram & Fine Proc, Beijing 100084, Peoples R China
来源：
MATERIALS RESEARCH BULLETIN | 2014年 / 59卷
基金：
中国国家自然科学基金;
关键词：
Ceramics; Ferroelectricity; Dielectric properties; Phase transitions; ELECTRICAL-PROPERTIES; ELECTROMECHANICAL PROPERTIES; SINGLE-CRYSTALS; GROWTH; TRANSFORMATION; HYSTERESIS; BEHAVIOR;
D O I：
10.1016/j.materresbull.2014.08.003
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
(1-x)[Pb(Mg1/3Nb2/3)O-3-PbTiO3 (65/35)]-xPbZrO(3) (PMN-PT-PZ) ceramics near morphotropic phase boundary with 0 <= x <= 0.10 were synthesized via the conventional solid-state reaction method. X-ray diffraction and variable temperature dielectric property characterization indicated that the rhombohedral to tetragonal phase transition temperature (T-rt) increased linearly with the increase of PZ constant. The composition and temperature dependence of their ferroelectric and pyroelectric properties were also investigated. The results showed that there appeared mutation for remnant polarization, coercive field, as well as pyroelectric coefficient at the temperate range near T-rt, which was ascribed to the reorientation of dipoles caused by the rhombohedral tetragonal phase transition. (C) 2014 Elsevier Ltd. All rights reserved.
引用
收藏
页码：421 / 424
页数：4
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