Crystal structure of the CeIr3 compound

被引:8
|
作者
Sologub, O
Salamakha, P [1 ]
Gonçalves, AP
Ipser, H
Almeida, A
机构
[1] Inst Tecnol & Nucl, Dept Quim, P-2686953 Sacavem, Portugal
[2] Univ Vienna, Inst Anorgan Chem, A-1090 Vienna, Austria
关键词
rare earth compounds; transition metal compounds; crystal structure; X-ray single crystal diffraction; cerium compound;
D O I
10.1016/j.jallcom.2003.11.007
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The crystal structure of the CeIr3 compound was refined for the first time from single-crystal X-ray diffraction data, down to R = 0.0490, wR2 = 0.1052. This compound crystallizes in the PuNi3 structure type, space group R (3) over barm (a = 5.290(2) Angstrom, c = 26.220(4) Angstrom, Z = 9, V = 635.44 Angstrom(3), rho = 16.835 g cm(-3), mu = 156.36 mm(-1)). CeIr3 belongs to the R2m+nM4m+5n family, where m and n are the numbers of MgCu2- and CaCu5-type slabs, respectively. For CeIr3, m and it were found to be both equal to 1. (C) 2003 Elsevier B.V. All rights reserved.
引用
收藏
页码:L5 / L7
页数:3
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