Synthesis and crystal structure of bis(4-methylpiperidine-dithiocarbamato-S,S′)-palladium(II)

被引：7
|
作者：
Shahzadi, Saira
Ali, Saqib
Badshah, Amin
Shaheen, Farkhanda
Ahmed, Fiaz
Fettouhi, Mohammed [1 ]
机构：
[1] King Fahd Univ Petr & Minerals, Dept Chem, Dhahran 31261, Saudi Arabia
[2] Quaid I Azam Univ, Dept Chem, Islamabad 45320, Pakistan
[3] NESCOM, Islamabad, Pakistan
来源：
JOURNAL OF CHEMICAL CRYSTALLOGRAPHY | 2006年 / 36卷 / 09期
关键词：
dithiocarbamate; palladium(II) complex; crystal structure;
D O I：
10.1007/s10870-006-9101-9
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The complex bis(4-methylpiperidine-dithiocarbamato-S,S')-palladium(II) was synthesized by the reaction of 4-methyl-1-piperidine dithiocarbamic acid with palladium(II) chloride. Its structure was determined by X-ray crystal diffraction analysis. It crystallizes in the monoclinic P2(1)/c space group with the crystal cell parameters a=8.6491(8)angstrom, b=18.7305(16) angstrom, c=11.9933(10) angstrom, beta=107.074(1)angstrom, V=1857.3(3) angstrom(3) and Z=4. The palladium (II) ion is bonded to four sulfur atoms, belonging to two dithiocarbamate ligands, in a distorted square planar geometry. The X-ray data suggest a pronounced electronic delocalization in the two NCS2 moieties.
引用
收藏
页码：567 / 570
页数：4
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