Chromium oxide supported on mesoporous SBA-15 as propane dehydrogenation and oxidative dehydrogenation catalysts

被引：104
|
作者：
Zhang, XZ [1 ]
Yue, YH [1 ]
Gao, Z [1 ]
机构：
[1] Fudan Univ, Dept Chem, Lab Mol Catalysis & Innovat Mat, Shanghai 200433, Peoples R China
来源：
CATALYSIS LETTERS | 2002年 / 83卷 / 1-2期
关键词：
SBA-15-supported Cr2O3 catalyst; C3H8; dehydrogenation; C3H8 oxidative dehydrogenation by O-2; C3H8 oxidative dehydrogenation by CO2;
D O I：
10.1023/A:1020693028720
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The catalytic activity and selectivity of Cr2O3 supported on mesoporous SBA-15 for non-oxidative and oxidative dehydrogenation of propane by O-2 and CO2 have been studied and compared with those of Cr2O3/ZrO2 and Cr2O3/gamma-Al2O3 catalysts. Cr2O3/SBA-15 and Cr2O3/ZrO2/SBA-15 are more selective to propene and more resistant to coking in comparison with Cr2O3/ZrO2 and Cr2O3/gamma-Al2O3 for non-oxidative dehydrogenation of propane. In oxidative dehydrogenation of propane by O-2 and CO2, Cr2O3/SBA-15 also displays better activity, selectivity and stability than the other two supported catalysts. The propane conversion and propene yield on Cr2O3/SBA-15 catalyst for oxidative dehydrogenation of propane by CO2 at 823 K reach 24.2 and 20.3%, respectively. XPS and TG/DTA have been used to characterize the catalysts before and after reaction. The differences in catalytic behavior of various supported Cr2O3 catalysts in the reactions have been discussed on the basis of the characterization results.
引用
收藏
页码：19 / 25
页数：7
相关论文
共 50 条
  • [1] Chromium Oxide Supported on Mesoporous SBA-15 as Propane Dehydrogenation and Oxidative Dehydrogenation Catalysts
    Xuezheng Zhang
    Yinghong Yue
    Zi Gao
    [J]. Catalysis Letters, 2002, 83 : 19 - 25
  • [2] Chromium Oxide supported on mesoporous SBA-15 as catalysts for oxidative dehydrogenation of propane by CO2
    Miao, JW
    Zhou, J
    Song, GH
    Fan, YN
    Gong, C
    [J]. CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2005, 21 (10) : 1541 - 1545
  • [3] Vanadium oxide supported on mesoporous SBA-15 as highly selective catalysts in the oxidative dehydrogenation of propane
    Liu, YM
    Cao, Y
    Yi, N
    Feng, WL
    Dai, WL
    Yan, SR
    He, HY
    Fan, KN
    [J]. JOURNAL OF CATALYSIS, 2004, 224 (02) : 417 - 428
  • [4] Highly efficient VOx/SBA-15 mesoporous catalysts for oxidative dehydrogenation of propane
    Liu, YM
    Cao, Y
    Zhu, KK
    Yan, SR
    Dai, WL
    He, HY
    Fan, KN
    [J]. CHEMICAL COMMUNICATIONS, 2002, (23) : 2832 - 2833
  • [5] Propane oxidative dehydrogenation over VOx/SBA-15 catalysts
    Mitran, Gheorghita
    Ahmed, Rawaz
    Iro, Emmanuel
    Hajimirzaee, Saeed
    Hodgson, Simon
    Urda, Adriana
    Olea, Maria
    Marcu, Ioan-Cezar
    [J]. CATALYSIS TODAY, 2018, 306 : 260 - 267
  • [6] Oxidative dehydrogenation of propane on silica (SBA-15) supported vanadia catalysts: A kinetic investigation
    Dinse, Arne
    Khennache, Sonia
    Frank, Benjamin
    Hess, Christian
    Herbert, Rita
    Wrabetz, Sabine
    Schloegl, Robert
    Schomaecker, Reinhard
    [J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2009, 307 (1-2) : 43 - 50
  • [7] Highly effective oxidative dehydrogenation of propane over vanadia supported on mesoporous SBA-15 silica
    Liu, YM
    Cao, Y
    Yan, SR
    Dai, WL
    Fan, KN
    [J]. CATALYSIS LETTERS, 2003, 88 (1-2) : 61 - 67
  • [8] Highly Effective Oxidative Dehydrogenation of Propane Over Vanadia Supported on Mesoporous SBA-15 Silica
    Yong-Mei Liu
    Yong Cao
    Shi-Run Yan
    Wei-Lin Dai
    Kang-Nian Fan
    [J]. Catalysis Letters, 2003, 88 : 61 - 67
  • [9] Nanostructured CoMoO4 supported on mesoporous SBA-15 for catalytic oxidative dehydrogenation of propane to propene
    Pei Su-Peng
    Zhang Bin
    Jiao Kun
    Bao Ren-Lie
    Yue Bin
    He He-Yong
    [J]. ACTA PHYSICO-CHIMICA SINICA, 2008, 24 (04) : 561 - 564
  • [10] Vanadia supported on H2O2-detemplated mesoporous SBA-15 as new effective catalysts for the oxidative dehydrogenation of propane
    Xu, Jie
    Chen, Miao
    Liu, Yong-Mei
    Cao, Yong
    He, He-Yong
    Fan, Kang-Nian
    [J]. MICROPOROUS AND MESOPOROUS MATERIALS, 2009, 118 (1-3) : 354 - 360
12345