Electronic structure and spin bonds in the [(NH3)(5)Cr-O-Cr(NH3)(5)](4+) complex

被引：1

作者：

Sizova, OV

Panin, AI

Baranovskii, VI

Shirokov, DV

机构：

[1] St. Petersburg State University,

来源：

JOURNAL OF STRUCTURAL CHEMISTRY | 1997年 / 38卷 / 03期

关键词：

D O I：

10.1007/BF02763601

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The electronic structure of the lowest singlet, triplet, quintet, and septet states of the binuclear complex [Cr(NH3)(5)](2)O4+ are calculated by the semiempirical MC SCF method in the INDO approximation. Schemes of spin coupling of Cr-O-Cr in these states are analyzed.

引用

页码：375 / 381

页数：7

共 50 条

[1] Electronic structure and spin bonds in the [(NH3)5Cr-O-Cr(NH3)5]4+ complex
O. V. Sizova
A. I. Panin
V. I. Baranovskii
D. V. Shirokov
[J]. Journal of Structural Chemistry, 1997, 38 : 375 - 381
[2] ELECTRONIC-STRUCTURE AND SPECTRA OF [RU(NH3)(5)PYZ](2+) AND [(NH3)(5)RU-PYZ-RU(NH3)(5)](4+)
SIZOVA, OV
IVANOVA, NV
BARANOVSKII, VI
NIKOLSKII, AB
[J]. JOURNAL OF STRUCTURAL CHEMISTRY, 1994, 35 (04) : 433 - 442
[3] SYNTHESIS OF TRANS[CR(NH3)4(NCS)2]+, TRANS[CR(NH3)4NCSF]+ AND [CR(NH3)5NCS]2+
KIRK, AD
WONG, CFC
[J]. INORGANICA CHIMICA ACTA, 1978, 27 (02) : 265 - 267
[4] THE PHOTOCHEMICAL AQUATION OF CR(NH3)6+3 AND CR(NH3)5H2O+3
EDELSON, MR
PLANE, RA
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1959, 63 (03): : 327 - 330
[5] Synthesis, crystal structure, and IR investigations of [(NH3)(5)V-O-V(NH3)(5)]I-4 center dot NH3 and [(NH3)(5)Ti-O-Ti(NH3)(5)]I-4 center dot NH3
Sichla, T
Niewa, R
Zachwieja, U
Essmann, R
Jacobs, H
[J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1996, 622 (12): : 2074 - 2078
[6] OPTICAL SPECTROSCOPY OF [(NH3)4CR(OH)2CR(NH3)4]4+ AND [(EN)2CR(OH)2CR(EN)2]4+
DECURTINS, S
GUDEL, HU
PFEUTI, A
[J]. INORGANIC CHEMISTRY, 1982, 21 (03) : 1101 - 1106
[7] THE CRYSTAL STRUCTURE OF [CR(NH3)6][CUCL5]
MORI, M
SAITO, Y
WATANABE, T
[J]. BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1961, 34 (02) : 295 - 296
[8] SPECTRAL PROPERTIES OF [(NH3)5CO(MU-O2)CO(NH3)5]4+ AND [(NH3)5CO(MU-O2)CO(NH3)5]5+ IONS - INTERPRETATION BY THE CDNO METHOD
BRONGEL, P
VOITSEKHOVSKI, V
CHERVINSKI, M
[J]. KOORDINATSIONNAYA KHIMIYA, 1988, 14 (12): : 1665 - 1671
[9] ORDERED BIMETALLIC MAGNETS - FERROMAGNETIC [CR(NH3)6][CR(CN)6] AND [CR(H2O)(NH3)5][CR(CN)6)]
CARLIN, RL
CARNEGIE, D
CASABO, J
[J]. JOURNAL OF APPLIED PHYSICS, 1984, 55 (06) : 2346 - 2346
[10] ELECTRONIC-STRUCTURE AND SPECTROSCOPIC PROPERTIES OF THE [(NH3)5CONH2CO(NH3)5]+5 COMPLEX ION
HYLAKRYSPIN, I
NATKANIEC, L
JEZOWSKATRZEBIATOWSKA, B
[J]. BULLETIN DE L ACADEMIE POLONAISE DES SCIENCES-SERIE DES SCIENCES CHIMIQUES, 1978, 26 (12): : 985 - 990

← 1 2 3 4 5 →