Conversion of fructose to 5-hydroxymethylfurfural catalyzed by coaled carbon-based solid acid

被引：2
|
作者：
Zheng, Ruiyuan [1 ]
Liu, Ning [1 ]
Liu, Wanyi [1 ]
Ma, Jingxin [1 ]
Li, Bing [1 ]
机构：
[1] Ningxia Univ, Sch Chem & Chem Engn, Yinchuan 750021, Peoples R China
来源：
APPLIED ENERGY TECHNOLOGY, PTS 1 AND 2 | 2013年 / 724-725卷
关键词：
coaled carbon-based solid acid; ultra-low ash Taixi coal; Sulfonation; D-fructose; 5-hydroxymethylfurfural; DEHYDRATION;
D O I：
10.4028/www.scientific.net/AMR.724-725.226
中图分类号：
TU [建筑科学];
学科分类号：
0813 ;
摘要：
Coaled carbon-based solid acid (Coal-SO3H) was prepared by sulfonating ultra-low ash Taixi coal and characterized by XPS, IR and PXRD. It was used as a new, efficient and recyclable catalyst for fructose dehydration to form 5-hydroxymethylfurfural (5-HMF) in dimethyl sulfoxide (DMSO). Reaction time, temperature and catalyst amounts were investigated respectively. The results showed that 81.6 % yield of 5-HMF achieved in dimethyl sulfoxide (DMSO) at 140 degrees C after 140min using the Coal-SO3H as catalyst. The ash, carbonization temperature and sulfonated way which could influence the catalyst performance for preparing 5-HMF had been investgated.
引用
收藏
页码：226 / 230
页数：5
相关论文
共 50 条
  • [1] Synthesis of 5-hydroxymethylfurfural from fructose catalyzed by sulfonated carbon-based solid acid
    He, Qiao
    Lu, Yuchan
    Peng, Qiao
    Chen, Wenhai
    Fan, Guozhi
    Chai, Bo
    Song, Guangsen
    [J]. BIOMASS CONVERSION AND BIOREFINERY, 2023, 13 (10) : 9195 - 9203
  • [2] Synthesis of 5-hydroxymethylfurfural from fructose catalyzed by sulfonated carbon-based solid acid
    Qiao He
    Yuchan Lu
    Qiao Peng
    Wenhai Chen
    Guozhi Fan
    Bo Chai
    Guangsen Song
    [J]. Biomass Conversion and Biorefinery, 2023, 13 : 9195 - 9203
  • [3] Hierarchical porous carbon-based solid acid as a high-performance catalyst for conversion of fructose to 5-hydroxymethylfurfural
    Zhang, Xingyilong
    Lu, Houfang
    Wu, Kejing
    Liu, Yingying
    Zhu, Yingming
    Liang, Bin
    [J]. FUEL, 2024, 363
  • [4] Conversion of fructose and glucose into 5-hydroxymethylfurfural catalyzed by a solid heteropolyacid salt
    Fan, Chunyan
    Guan, Hongyu
    Zhang, Hang
    Wang, Jianghua
    Wang, Shengtian
    Wang, Xiaohong
    [J]. BIOMASS & BIOENERGY, 2011, 35 (07): : 2659 - 2665
  • [5] Efficient catalytic conversion of fructose into hydroxymethylfurfural by a novel carbon-based solid acid
    Wang, Jianjian
    Xu, Wenjie
    Ren, Jiawen
    Liu, Xiaohui
    Lu, Guanzhong
    Wang, Yanqin
    [J]. GREEN CHEMISTRY, 2011, 13 (10) : 2678 - 2681
  • [6] Conversion of fructose into 5-hydroxymethylfurfural and alkyl levulinates catalyzed by sulfonic acid-functionalized carbon materials
    Liu, Ruliang
    Chen, Jinzhu
    Huang, Xing
    Chen, Limin
    Ma, Longlong
    Li, Xinjun
    [J]. GREEN CHEMISTRY, 2013, 15 (10) : 2895 - 2903
  • [7] Bifunctional Solid Catalysts for the Selective Conversion of Fructose to 5-Hydroxymethylfurfural
    Anthony J. Crisci
    Mark H. Tucker
    James A. Dumesic
    Susannah L. Scott
    [J]. Topics in Catalysis, 2010, 53 : 1185 - 1192
  • [8] Bifunctional Solid Catalysts for the Selective Conversion of Fructose to 5-Hydroxymethylfurfural
    Crisci, Anthony J.
    Tucker, Mark H.
    Dumesic, James A.
    Scott, Susannah L.
    [J]. TOPICS IN CATALYSIS, 2010, 53 (15-18) : 1185 - 1192
  • [9] Efficient Conversion of Glucose into 5-Hydroxymethylfurfural Using a Sulfonated Carbon-Based Solid Acid Catalyst: An Experimental and Numerical Study
    Nahavandi, Milad
    Kasanneni, Tirumala
    Yuan, Zhongshun Sean
    Xu, Chunbao Charles
    Rohani, Sohrab
    [J]. ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2019, 7 (14): : 11970 - 11984
  • [10] Synthesis of 5-hydroxymethylfurfural from fructose catalyzed by phosphotungstic acid
    Gomes, Filipe N. D. C.
    Mendes, Fabiana M. T.
    Souza, Mariana M. V. M.
    [J]. CATALYSIS TODAY, 2017, 279 : 296 - 304
12345