Syntheses and crystal structures of copper and silver complexes containing dithiophosphinato and trithiophosphonato ligands

被引：25
|
作者：
Fenske, D [1 ]
Rothenberger, A [1 ]
Fallah, MS [1 ]
机构：
[1] Univ Karlsruhe, Inst Anorgan Chem, D-76131 Karlsruhe, Germany
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2004年 / 630卷 / 06期
关键词：
copper; silver; P ligands; S ligands; crystal structures;
D O I：
10.1002/zaac.200400049
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The reactions of Cu-1 and Ag-1 salts with diphenyldithiophosphinic acid trirnethylsilylester in the presence of tertiary phosphines yield the complexes [Cu(mu-S)SPPh2(PR3)](2) (R = Me 1a, 'Pr 1b), [A(mu-S)SPPh2((PPr3)-Pr-n)](2) (2), [Ag(S2PPh2)(PEt3)](2) (3), and [Cu-8(mu(8)-S)(S2PPh2)6] (4). The cage complex [(PhPS3)(2)Cu-4(PMe3)(5)] (5) is obtained by the reaction of phenyltrithiophosphonic acid trimethylester. All compounds were structurally characterised by Xray crystallography.
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收藏
页码：943 / 947
页数：5
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