Electrochemical Oxidation of 5-Hydroxymethylfurfural with NiFe Layered Double Hydroxide (LDH) Nanosheet Catalysts

被引:385
|
作者
Liu, Wu-Jun [1 ,2 ]
Dang, Lianna [3 ]
Xu, Zhuoran [1 ]
Yu, Han-Qing [2 ]
Jin, Song [3 ]
Huber, George W. [1 ]
机构
[1] Univ Wisconsin, Dept Chem & Biol Engn, Madison, WI 53706 USA
[2] Univ Sci & Technol China, Dept Chem, CAS Key Lab Urban Pollutant Convers, Hefei 230026, Anhui, Peoples R China
[3] Univ Wisconsin, Dept Chem, 1101 Univ Ave, Madison, WI 53706 USA
来源
ACS CATALYSIS | 2018年 / 8卷 / 06期
基金
美国国家科学基金会;
关键词
electrochemical oxidation; HMF; FDCA; NiFe LDH; biomass conversion; OXYGEN EVOLUTION CATALYSTS; 2,5-FURANDICARBOXYLIC ACID; HYDROGEN-PRODUCTION; AEROBIC OXIDATION; WATER OXIDATION; BIFUNCTIONAL ELECTROCATALYST; MOSSBAUER-SPECTROSCOPY; BIOMASS VALORIZATION; SUPPORTED AU; NANOPARTICLES;
D O I
10.1021/acscatal.8b01017
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Electrochemical oxidation of biomass-derived platform molecules can enable the production of value-added oxygenated commodity chemicals under mild conditions in a distributed fashion using renewable electricity; however, very few efficient, robust, and inexpensive electrocatalysts are available for such electrochemical oxidation. Here we demonstrate that earth-abundant NiFe layered double hydroxide (LDH) nanosheets grown on carbon fiber paper can efficiently catalyze the oxidation of 5-hydroxymethylfurfural (HMF) to 2,5-furandicarboxylic acid (FDCA) at the anode of an electrochemical cell. A near-quantitative yield of FDCA and 99.4% Faradaic efficiency of HMF conversion under ambient conditions can be achieved in the electrochemical process. HMF has a higher rate of oxidation than water and can act as an alternative anodic reaction for alkaline H-2 evolution in water-splitting cells. As the first report on using bimetallic metal hydroxide/oxide catalysts for electrochemical oxidation of HMF, this work opens up opportunities in electrochemical devices to simultaneously produce building-block chemicals from biomass-derived molecules and clean H-2 fuels under ambient conditions with earth-abundant materials.
引用
收藏
页码:5533 / 5541
页数:17
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