Selective and sensitive fluorescent turn-off chemosensors for Fe3+

被引:36
|
作者
Fu, Li [1 ,2 ]
Mei, Jie [1 ,2 ]
Zhang, Ji-Tao [1 ,2 ]
Liu, Yi [1 ,2 ]
Jiang, Feng-Lei [1 ,2 ]
机构
[1] Wuhan Univ, Coll Chem & Mol Sci, State Key Lab Virol, Wuhan 430072, Peoples R China
[2] Wuhan Univ, Coll Chem & Mol Sci, Minist Educ, Key Lab Analyt Chem Biol & Med, Wuhan 430072, Peoples R China
基金
中国国家自然科学基金;
关键词
l-histidine; chemosensor; anthracene; dansyl; Fe3+; SENSORS; BINDING; RECOGNITION; COPPER(II); MECHANISMS; PROBES; CELLS; WATER; ACIDS; BASE;
D O I
10.1002/bio.2406
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Two novel chemosensors (2a and 2b) were synthesized by facile condensation of the binding unit (l-histidine) and the fluorophores (anthracene and dansyl groups). Both of them displayed high selectivity and sensitivity towards Fe3+ over other metal ions in aqueous solution. (3+) that would lead to fluorescence quenching of the fluorophores when Fe3+ was bound to the recognition units. l-histidine was a good coordination motif for Fe3+ and both the anthracene and dansyl groups can sensitively report the sensing information. Copyright (c) 2012 John Wiley & Sons, Ltd.
引用
收藏
页码:602 / 606
页数:5
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