Processing of carbon composite paper as electrode for fuel cell

被引:92
|
作者
Mathur, R. B.
Maheshwari, Priyanka H.
Dhami, T. L.
Sharma, R. K.
Sharma, C. P.
机构
[1] Natl Phys Lab, Carbon Technol Unit, New Delhi 110012, India
[2] Natl Phys Lab, Soft Polymer Grp, Div Engn Mat, New Delhi 110012, India
关键词
carbon fibres; fuel cell; porosity; electrical properties; paper-making; composite;
D O I
10.1016/j.jpowsour.2006.05.053
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The porous carbon electrode in a fuel cell not only acts as an electrolyte and a catalyst support, but also allows the diffusion of hydrogen fuel through its fine porosity and serves as a current-carrying conductor. A suitable carbon paper electrode is developed and possesses the characteristics of high porosity, permeability and strength along with low electrical resistivity so that it can be effectively used in proton-exchange membrane and phosphoric acid fuel cells. The electrode is prepared through a combination of two important techniques, viz., paper-making technology by first forming a porous chopped carbon fibre preform, and composite technology using a thermosetting resin matrix. The study reveals an interdependence of one parameter on another and how judicious choice of the processing conditions are necessary to achieve the desired characteristics. The current-voltage performance of the electrode in a unit fuel cell matches that of a commercially-available material. (c) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码:790 / 798
页数:9
相关论文
共 50 条
  • [1] Carbon fiber paper for fuel cell electrode
    Duan Qiongjuan
    Wang Jiong
    Wang Biao
    Wang Huaping
    [J]. PROCEEDINGS OF 2009 INTERNATIONAL CONFERENCE ON ADVANCED FIBERS AND POLYMER MATERIALS, VOLS 1 AND 2, 2009, : 461 - 463
  • [2] Carbon fiber paper for fuel cell electrode
    Zhang, XJ
    Shen, ZM
    [J]. FUEL, 2002, 81 (17) : 2199 - 2201
  • [3] Carbon fiber paper for fuel cell electrode.
    Zhang, XJ
    Shen, ZM
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2001, 222 : U467 - U467
  • [4] Direct Synthesis of Nitrogen-containing Carbon Nanotubes on carbon Paper for Fuel Cell Electrode
    Yin, Wong Wai
    Daud, Wan Ramli Wan
    Mohamad, Abu Bakar
    Kadhum, Abdul Amir Hassan
    Majlan, Edy Herianto
    Shyuan, Loh Kee
    [J]. 2ND ASEAN - APCTP WORKSHOP ON ADVANCED MATERIALS SCIENCE AND NANOTECHNOLOGY (AMSN 2010), 2012, 1455 : 181 - 186
  • [5] Carbon Nanotube Composite Electrode Coated with Polypyrrole for Microbial Fuel Cell Application
    Roh, Sung-Hee
    Woo, Hee-Gweon
    [J]. JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY, 2015, 15 (01) : 484 - 487
  • [6] Composite fuel for direct carbon fuel cell
    Dudek, Magdalena
    Tomczyk, Piotr
    [J]. CATALYSIS TODAY, 2011, 176 (01) : 388 - 392
  • [7] Improved performance of a microbial fuel cell with polypyrrole/carbon black composite coated carbon paper anodes
    Yuan, Yong
    Kim, Sunghyun
    [J]. BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 2008, 29 (07) : 1344 - 1348
  • [8] Improved performance of PEM fuel cell using carbon paper electrode prepared with CNT coated carbon fibers
    Maheshwari, Priyanka H.
    Mathur, R. B.
    [J]. ELECTROCHIMICA ACTA, 2009, 54 (28) : 7476 - 7482
  • [9] The influence of the pore size and its distribution in a carbon paper electrode on the performance of a PEM Fuel cell
    Maheshwari, Priyanka H.
    Mathur, R. B.
    Dhami, T. L.
    [J]. ELECTROCHIMICA ACTA, 2008, 54 (02) : 655 - 659
  • [10] Improved properties of carbon fiber paper as electrode for fuel cell by coating pyrocarbon via CVD method
    谢志勇
    金谷英
    张敏
    苏哲安
    张明瑜
    陈建勋
    黄启忠
    [J]. Transactions of Nonferrous Metals Society of China, 2010, 20 (08) : 1412 - 1417