Electrical and Dielectric Properties of Foam Injection-Molded Polypropylene/Multiwalled Carbon Nanotube Composites

A combination of high dielectric permittivity (epsilon') and low dielectric loss (tan delta) is required for charge storage applications. In percolative systems such as conductive polymer composites, however, obtaining high epsilon' and low tan delta is very challenging due to the sharp insulation-conduction transition near the threshold region. Due to the particular arrangement of conductive fillers induced by both foaming and injection molding processes, they may address this issue. Therefore, this work evaluates the application of foam injection molding process in fabricating polymer nanocomposites for energy storage. Polypropylene-multiwalled carbon nanotubes (PP-MWCNT) composites were prepared by melt mixing and foamed in an injection molding process. Electrical conductivity (sigma), epsilon' and tan delta were then characterized. Also, scanning and transmission electron microscopy (SEM and TEM) was used to investigate the carbon nanotube's arrangement as well as cellular morphology. The results showed that foam injection-molded composites exhibited highly superior dielectric properties to those of solid counterparts. For instance, foamed samples had epsilon'= 68.3 and tan delta = 0.05 (at 1.25 vol.% MWCNT), as opposed to epsilon'= 17.8 and tan delta= 0.04 in solid samples (at 2.56 vol.% MWCNT). The results of this work reveal that high performance dielectric nanocomposites can be developed using foam injection molding technologies for charge storage applications.