Ring-closing metathesis strategies to P-heterocycles

被引：0

作者：

Sprott, KT ^{[1
]}

McReynolds, MD ^{[1
]}

Hanson, PR ^{[1
]}

机构：

[1] Univ Kansas, Dept Chem, Lawrence, KS 66045 USA

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 2002年 / 177卷 / 6-7期

关键词：

1,4-diamine; P-heterocycle; ring-closing metathesis cyclic phosphonamide; temporary phosphorus tether;

D O I：

10.1080/10426500212282

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A general approach to the synthesis of P-heterocycles using the ring-closing metathesis reaction is described. We have developed a new method utilizing phosphorus nuclei as suitable temporary tethers for the coupling of non-racemic allylic amines. This approach allows for the generation of symmetric and unsymmetric 1,4-diamines. Subsequent coupling of these 1,4-diamines with various nuclei produces an array of 7-membered heterocycles.

引用

页码：1807 / 1809

页数：3

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