A Family of Metal-Organic Frameworks Exhibiting Size-Selective Catalysis with Encapsulated Noble-Metal Nanoparticles

被引：389
|
作者：
Zhang, Weina [3 ]
Lu, Guang [3 ,6 ]
Cui, Chenlong [3 ]
Liu, Yayuan [3 ]
Li, Shaozhou [3 ]
Yan, Wenjin [4 ]
Xing, Chong [5 ]
Chi, Yonggui Robin [5 ]
Yang, Yanhui [4 ]
Huo, Fengwei [1 ,2 ,3 ]
机构：
[1] Nanjing Tech Univ, Singapore Jiangsu Joint Res Ctr Organ Bioelect &, Nanjing 211816, Jiangsu, Peoples R China
[2] Nanjing Tech Univ, IAM, Nanjing 211816, Jiangsu, Peoples R China
[3] Nanyang Technol Univ, Sch Mat Sci & Engn, Singapore 639798, Singapore
[4] Nanyang Technol Univ, Sch Chem & Biomed Engn, Singapore 637459, Singapore
[5] Nanyang Technol Univ, Sch Phys & Math Sci, Singapore 637371, Singapore
[6] Soochow Univ, Inst Funct Nano & Soft Mat, Suzhou 215123, Peoples R China
来源：
ADVANCED MATERIALS | 2014年 / 26卷 / 24期
基金：
新加坡国家研究基金会;
关键词：
metal-organic frameworks; noble-metal nanoparticles; nanoparticles; composites; selective catalysis; HYDROGEN STORAGE; SHELL; SILICA;
D O I：
10.1002/adma.201400620
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The encapsulation of noble-metal nanoparticles (NPs) in metal-organic frameworks (MOFs) with carboxylic acid ligands, the most extensive branch of the MOF family, gives NP/MOF composites that exhibit excellent shape-selective catalytic performance in olefin hydrogenation, aqueous reaction in the reduction of 4-nitrophenol, and faster molecular diffusion in CO oxidation. The strategy of using functionalized cavities of MOFs as hosts for different metal NPs looks promising for the development of high-performance heterogeneous catalysts. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：4056 / 4060
页数：5
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