Isobaric vapour-liquid equilibria for the binary systems 4-methyl-2-pentanone+1-butanol and+2-butanol at 20 and 101.3 kPa

被引：20

作者：

Martinez, Nelson F. ^{[1
]}

Lladosa, Estela ^{[1
]}

Burguet, M. Cruz ^{[1
]}

Monton, Juan B. ^{[1
]}

Yazimon, Marlen ^{[1
,2
]}

机构：

[1] Univ Valencia, Escuela Tecn Super Ingn, Dept Ingn Quim, Valencia 46100, Spain

[2] Dept Genie Chim & Genie Procedes, Lyon, France

来源：

FLUID PHASE EQUILIBRIA | 2009年 / 277卷 / 01期

关键词：

Vapour-liquid equilibria; 4-Methyl-2-pentanone; 1-Butanol; 2-Butanol; MIXTURES; EXPRESSION; ENERGY;

D O I：

10.1016/j.fluid.2008.11.012

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Isobaric vapour-liquid equilibrium (VLE) measurements for the binary systems 4-methyl-2-pentanone + 1-butanol and 4-methyl-2-pentanone + 2-butanol are reported at 20 and 101.3 kPa. The system 4-methyl-2-pentanone + 1-butanol presents a minimum boiling point azeotrope at both pressures (20 and 101.3 kPa) and the system 4-methyl-2-pentanone + 2-butamol presents only a minimum boiling azeotrope at 20 kPa. In both systems, which deviate positively from ideal behaviour, the azeotropic composition is strongly dependent on pressure. The activity coefficients and boiling points of the solutions were correlated with its composition by the Wilson. UNIQUAC, and NRTL models for which the parameters are reported. (c) 2008 Elsevier B.V. All rights reserved.

引用

页码：49 / 54

页数：6

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