Recent developments in epoxide preparation

被引：27

作者：

Sello, G. ^{[1
]}

Fumagalli, Tiziano ^{[1
]}

Orsini, F. ^{[1
]}

机构：

[1] Univ Milan, Dipartimento Chim Organ & Ind, I-20133 Milan, Italy

来源：

CURRENT ORGANIC SYNTHESIS | 2006年 / 3卷 / 04期

关键词：

epoxide synthesis; metals-mediated reactions; ketone-mediated reactions; epoxides from carbonyls; enzymatic reactions; enantioselective preparations;

D O I：

10.2174/157017906778699503

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

This review will present recent achievements in the use of novel reactants and synthetic procedures for the transformation of substrates into epoxide derivatives. This will include both classical chemical methods using novel catalysts and/or cleaner methodologies, and enzymatic preparations using enzymes or cells. Special attention is paid to the preparation of chiral compounds. A comparison of the advantages and disadvantages of the different preparations is also included.

引用

页码：457 / 476

页数：20

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