Hydrogen atom recombination on tungsten at high temperature: Experiment and Molecular Dynamics Simulation

被引:5
|
作者
Rutigliano, M. [1 ]
Santoro, D. [1 ]
Balat-Pichelin, M. [2 ]
机构
[1] CNR IMIP, Ist Metodol Inorgan & Plasmi, I-70126 Bari, Italy
[2] PROMES CNRS, Lab Proc Mat & Energie Solaire, F-66120 Font Romeu, France
关键词
Hydrogen plasma; Atom recombination; Tungsten; Molecular Dynamics Simulation; Magnetically confined fusion plasma; EMISSION-SPECTROSCOPY; OXYGEN RECOMBINATION; H-ATOMS; H-2; PLASMA; INTENSITIES; ADSORPTION; DENSITY; SURFACE; W(110);
D O I
10.1016/j.susc.2014.05.007
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Atom recombination at wall is a phenomenon involved in many plasma experiments and also in present tokamaks and future fusion plasma reactors like ITER. This exothermic surface reaction is catalyzed by the material and depends on its composition and temperature. In the MESOX experimental set-up, several methods were developed for the measurement of the recombination parameters. In this paper, a method developed for the experimental evaluation of the recombination coefficient of atomic hydrogen gamma(H) on tungsten at high temperature is presented using two series of atomic lines (H alpha and He or H beta and H-2) and the results obtained for surface temperature up to 1350 K are given. A Molecular Dynamics Simulation has been done for the recombination of hydrogen atoms on tungsten in conditions close to the experimental ones using a semi-classical collisional method. Modeling results are compared to the experimental data for two surface temperature values and a fairly good agreement was obtained. (C) 2014 Elsevier B.V. All rights reserved.
引用
收藏
页码:66 / 75
页数:10
相关论文
共 50 条
  • [1] Recombination coefficient of atomic oxygen on silica surfaces at high temperature: Experiment and molecular dynamics simulation
    Cacciatore, M
    Rutigliano, M
    Armenise, I
    Balat-Pichelin, M
    Badie, JM
    [J]. 4TH EUROPEAN SYMPOSIUM ON AEROTHERMODYNAMICS FOR SPACE VEHICLES, PROCEEDINGS, 2002, 487 : 497 - 503
  • [2] Semiclassical molecular dynamics simulation of surface processes: Application to the hydrogen atom recombination on graphite
    Cacciatore, M
    Rutigliano, M
    [J]. INTERNATIONAL JOURNAL OF QUANTUM CHEMISTRY, 2006, 106 (03) : 631 - 635
  • [3] Molecular Dynamics Simulation on Hydrogen Trapping on Tungsten Vacancy
    Nakamura, Hiroaki
    Takasan, Kazuki
    Yajima, Miyuki
    Saito, Seiki
    [J]. JOURNAL OF ADVANCED SIMULATION IN SCIENCE AND ENGINEERING, 2023, 10 (01): : 132 - 143
  • [4] Molecular dynamics simulation of hydrogen and helium trapping in tungsten
    Grigorev, Petr
    Zinovev, Aleksandr
    Terentyev, Dmitry
    Bonny, Giovanni
    Zhurkin, Evgeny E.
    Van Oost, Guido
    Noterdaeme, Jean-Marie
    [J]. JOURNAL OF NUCLEAR MATERIALS, 2018, 508 : 451 - 458
  • [5] RECOMBINATION DYNAMICS OF HYDROGEN ON A TUNGSTEN SURFACE
    MCCREERY, JH
    WOLKEN, G
    [J]. JOURNAL OF CHEMICAL PHYSICS, 1975, 63 (09): : 4072 - 4073
  • [6] Atomic oxygen recombination on quartz at high temperature: Experiments and molecular dynamics simulation
    Bedra, L.
    Rutigliano, M.
    Balat-Pichelin, M.
    Cacciatore, M.
    [J]. LANGMUIR, 2006, 22 (17) : 7208 - 7216
  • [7] Classical molecular dynamics simulation of the interaction of hydrogen with defects in tungsten
    Grigorev P.Y.
    Terentyev D.A.
    Bakaev A.V.
    Zhurkin E.E.
    [J]. Journal of Surface Investigation. X-ray, Synchrotron and Neutron Techniques, 2016, 10 (2) : 398 - 405
  • [8] DYNAMICS OF ATOM-ADSORBED ATOM COLLISIONS - HYDROGEN ON TUNGSTEN
    ELKOWITZ, AB
    MCCREERY, JH
    WOLKEN, G
    [J]. CHEMICAL PHYSICS, 1976, 17 (04) : 423 - 431
  • [9] Molecular dynamics simulation of hydrogen dissolution and diffusion in a tungsten grain boundary
    Yu, Yi
    Shu, Xiaolin
    Liu, Yi-Nan
    Lu, Guang-Hong
    [J]. JOURNAL OF NUCLEAR MATERIALS, 2014, 455 (1-3) : 91 - 95
  • [10] Molecular Dynamics Simulation of the Chemical Interaction between Hydrogen Atom and Graphene
    Ito, Atsushi
    Nakamura, Hiroaki
    Takayama, Arimichi
    [J]. JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN, 2008, 77 (11)