2-Bromo-N-(2-chlorophenyl)acetamide

被引:2
|
作者
Gowda, B. Thimme [1 ]
Foro, Sabine [2 ]
Suchetan, P. A. [1 ]
Fuess, Hartmut [2 ]
Terao, Hiromitsu [3 ]
机构
[1] Mangalore Univ, Dept Chem, Mangalore 574199, India
[2] Tech Univ Darmstadt, Inst Mat Sci, D-64287 Darmstadt, Germany
[3] Univ Tokushima, Fac Integrated Arts & Sci, Tokushima 7708502, Japan
关键词
D O I
10.1107/S1600536809028918
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The conformation of the N-H bond in the structure of the title compound, C8H7BrClNO, is syn to the 2-chloro substituent in the aniline ring and anti to both the C=O and C-Br bonds in the side chain, similar to that observed in 2-chloro-N-(2-chlorophenyl)acetamide. In the crystal, molecules are linked into chains along the a axis by N-H center dot center dot center dot O hydrogen bonds. These chains are in turn linked into pairs, in the form of columns, through much weaker C-H center dot center dot center dot Cl and Br center dot center dot center dot Br [4.3027 (3) angstrom] interactions.
引用
收藏
页码:O1998 / U4186
页数:8
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