Group 10 derivatives of the silylated sterically hindered aromatic thiolates [C6H4SH-2-SiPh3] and [C6H4SH-2-SiCH3Ph2].: The crystal structures of trans-[Pd(PPh3)2(SC6H4-2-SiPh3)2], z-[Pt(PPh3)2(Cl)(Sc6H4-2-SiPh3)], e-[Pt(PPh3)2(Cl)-(SC6H4-2-SiCH3Ph2)], cis-[Pt(PPh3)2(SC6H4-2-SiCH3Ph2)2], trans-[Pt(PPh3)2(SC6H4-2-SiCH3Ph2)2]

被引：9

作者：

Cordero-Pensado, Viviana ^{[1
]}

Gomez-Benitez, Valente ^{[1
]}

Hernandez-Ortega, Simon ^{[1
]}

Toscano, Ruben A. ^{[1
]}

Morales-Morales, David ^{[1
]}

机构：

[1] Natl Autonomous Univ Mexico, Inst Quim, Mexico City 04510, DF, Mexico

来源：

INORGANICA CHIMICA ACTA | 2006年 / 359卷 / 12期

关键词：

sterically hindered thiols; thiolate complexes; palladium complexes; crystal structures;

D O I：

10.1016/j.ica.2006.05.018

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reactivity of the silylated sterically hindered thiolates [C6H4SH-2-SiPh3] and [C6H4SH-2-SiCH3Ph2] has been examined with transition metal complexes of group 10. A series of palladium(II) and platinum(II) complexes were obtained. Analysis of these complexes by different spectroscopic techniques and single crystal X-ray diffraction studies revealed the formulations to be dependent of the stoichiometry and relative size of the metal center and thiolate. Analogous reactions with nickel complexes afforded oxidation decomposition products. (c) 2006 Elsevier B.V. All rights reserved.

引用

页码：4007 / 4018

页数：12

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