BBr3-promoted cyclization to produce ladder-type conjugated polymer

被引:17
|
作者
Kim, Inja
Kim, Tae-Hyun
Kang, Youngjin
Lim, Yong-beom
机构
[1] Univ Incheon, Dept Chem, Inchon 402749, South Korea
[2] Kangweon Natl Univ, Div Sci Educ, Chunchon 200701, South Korea
[3] Yonsei Univ, Dept Chem, Seoul 120749, South Korea
关键词
D O I
10.1016/j.tetlet.2006.10.020
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A novel chemical cyclization method using BBr3 has been successfully developed to prepare ladder-type conjugated systems. The cyclized ladder compounds revealed an extended conjugation due to planarization of the structures. The extended ladder polymer can also be easily prepared by our chemical cyclization method using a soluble precursor. (c) 2006 Elsevier Ltd. All rights reserved.
引用
收藏
页码:8689 / 8692
页数:4
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