The electronic structure of carbonate ion in aqueous solution studied by soft X-ray emission spectroscopy

被引：8
|
作者：
Horikawa, Y. [1 ,2 ]
Yoshida, A. [3 ]
Takahashi, O. [4 ]
Arai, H. [1 ]
Tokushima, T. [1 ]
Gejo, T. [3 ]
Shin, S. [1 ,2 ]
机构：
[1] RIKEN SPring 8 Ctr, Sayo, Hyogo 6795148, Japan
[2] Univ Tokyo, Inst Solid State Phys, Kashiwa, Chiba 2778581, Japan
[3] Univ Hyogo, Kobe, Hyogo 6781297, Japan
[4] Hiroshima Univ, Inst Sustainable Sci & Dev, Hiroshima 7398526, Japan
来源：
JOURNAL OF MOLECULAR LIQUIDS | 2014年 / 189卷
基金：
日本学术振兴会;
关键词：
Carbonate ion; Soft X-rays; X-ray emission spectroscopy; Valence electronic states; Molecular orbital calculation; SURFACES;
D O I：
10.1016/j.molliq.2013.06.021
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
X-ray absorption and emission spectra of carbonate ions in aqueous solution were measured at two concentrations. The signals from the ion were extracted via selective excitation and background subtraction. The obtained spectral shape for the emission of the ion was well explained by DFT calculations. (C) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码：9 / 12
页数：4
相关论文
共 50 条
  • [1] Electronic structure of BP studied by resonant soft X-ray emission spectroscopy
    Agui, A
    Shin, S
    Kumashiro, Y
    [J]. JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN, 1999, 68 (01) : 166 - 169
  • [2] Electronic Structure of Hemin in Solution Studied by Resonant X-ray Emission Spectroscopy and Electronic Structure Calculations
    Atak, Kaan
    Golnak, Ronny
    Xiao, Jie
    Suljoti, Edlira
    Pflueger, Mika
    Brandenburg, Tim
    Winter, Bernd
    Aziz, Emad F.
    [J]. JOURNAL OF PHYSICAL CHEMISTRY B, 2014, 118 (33): : 9938 - 9943
  • [3] Electronic structure of CdO studied by soft X-ray spectroscopy
    Demchenko, I. N.
    Chernyshova, M.
    Tyliszczak, T.
    Denlinger, J. D.
    Yu, K. M.
    Speaks, D. T.
    Hemmers, O.
    Walukiewicz, W.
    Derkachov, G.
    Lawniczak-Jablonska, K.
    [J]. JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA, 2011, 184 (3-6) : 249 - 253
  • [4] Electronic structure of aluminium trihydride studied using soft x-ray emission and absorption spectroscopy
    Takeda, Y.
    Saitoh, Y.
    Saitoh, H.
    Machida, A.
    Aoki, K.
    Yamagami, H.
    Muro, T.
    Kato, Y.
    Kinoshita, T.
    [J]. PHYSICAL REVIEW B, 2011, 84 (15)
  • [5] The electronic structure of perfluorodecalin studied by soft X-ray spectroscopy and electronic structure calculations
    Brandenburg, T.
    Agaker, M.
    Atak, K.
    Pflueger, M.
    Schwanke, C.
    Petit, T.
    Lange, K. M.
    Rubensson, J. -E.
    Aziz, E. F.
    [J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2014, 16 (42) : 23379 - 23385
  • [6] Electronic structure of advanced materials studied by X-ray emission spectroscopy
    [J]. Poverkhnost Fiz Khim Mekh, 4-5 (222):
  • [7] Electronic Structure of Sulfur Studied by X-ray Absorption and Emission Spectroscopy
    Mori, R. Alonso
    Paris, E.
    Giuli, G.
    Eeckhout, S. G.
    Kavcic, M.
    Zitnik, M.
    Bucar, K.
    Pettersson, L. G. M.
    Glatzel, P.
    [J]. ANALYTICAL CHEMISTRY, 2009, 81 (15) : 6516 - 6525
  • [8] Electronic structure of advanced materials studied by x-ray emission spectroscopy
    Kurmaev, EZ
    Galakhov, VR
    Yarmoshenko, YM
    Trofimova, VA
    Shamin, SN
    Cherkashenko, VM
    Poteryaev, AI
    Anisimov, VI
    [J]. X-RAY AND INNER-SHELL PROCESSES - 17TH INTERNATIONAL CONFERENCE, 1997, (389): : 771 - 785
  • [9] Electronic structure of advanced materials studied by X-ray emission spectroscopy
    Kurmaev, E.Z.
    Galakhov, V.R.
    Yarmoshenko, Yu.M.
    Trofimova, V.A.
    Shamin, S.N.
    Cherkashenko, V.M.
    Poteryaev, A.I.
    Anisimov, V.I.
    [J]. Surface Investigation X-Ray, Synchrotron and Neutron Techniques, 1998, 13 (4-5): : 637 - 649
  • [10] Anisotropic electronic structure of NaAlSi studied by angle-resolved soft x-ray emission spectroscopy
    Ebisu, Ryogo
    Sato, Yohei K.
    Yamada, Takahiro
    Terauchi, Masami
    [J]. JOURNAL OF APPLIED PHYSICS, 2023, 134 (21)
12345