Adaptive behavior of a redox-active gallium carbenoid in complexes with molybdenum

被引：24
|
作者：
Fedushkin, Igor L. [1 ,2 ]
Sokolov, Vladimir G. [1 ,2 ]
Piskunov, Alexander V. [1 ,2 ]
Makarov, Valentine M. [3 ]
Baranov, Eugeny V. [1 ,2 ]
Abakumov, Gleb A. [1 ,2 ]
机构：
[1] Russian Acad Sci, GA Razuvaev Inst Organometall Chem, Nizhnii Novgorod 603950, Russia
[2] NI Lobachevskii Nizhny Novgorod State Univ, Nizhnii Novgorod 603950, Russia
[3] K Minin Nizhny Novgorod State Pedag Univ, Nizhnii Novgorod 603950, Russia
来源：
CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 70期
基金：
俄罗斯科学基金会;
关键词：
CP-ASTERISK-GA; STRUCTURAL-CHARACTERIZATION; ELECTRON-TRANSFER; LIGAND; METAL; EPR; HETEROCYCLES; DIGALLANE;
D O I：
10.1039/c4cc04019h
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A gallium(I) carbenoid derived from redox-active diimine 1,2-bis[(2,6-diisopropylphenyl) imino]acenaphthene (dpp-bian) in complexes with molybdenum may serve either as a neutral [(dpp-bian)Ga:] or an anionic [(dpp-bian)Ga:](-) two-electron donor depending on the electronic state of the transition metal.
引用
收藏
页码：10108 / 10111
页数：4
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