Non-conventional Lewis Acids and Bases in Frustrated Lewis Pair Chemistry

被引：7
|
作者：
Caputo, Christopher B. [1 ]
Stephan, Douglas W. [1 ]
机构：
[1] Univ Toronto, Dept Chem, Toronto, ON M5S3H6, Canada
来源：
CHEMICAL BOND III: 100 YEARS OLD AND GETTING STRONGER | 2017年 / 171卷
关键词：
Activation of small molecules; Catalysis; Frustrated Lewis pairs; Lewis acids; Lewis bases; HETEROLYTIC DIHYDROGEN ACTIVATION; N-HETEROCYCLIC CARBENE; METAL-FREE; HEXACOORDINATE PHOSPHORUS; C-H; CATALYZED HYDROGENATION; IMINE HYDROGENATION; CRYSTAL-STRUCTURE; ROOM-TEMPERATURE; BOND ACTIVATION;
D O I：
10.1007/430_2015_177
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The discovery of frustrated Lewis pairs (FLPs) was based on the reactions of combinations of sterically demanding phosphine donors and electrophilic boranes with dihydrogen. Since these early findings, the range of species that exhibit FLP chemistry has broadened dramatically to include a series of Lewis acids and bases. In this review, we describe a variety of such systems and the corresponding reactivity of FLPs derived from group 13-16 species.
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页码：1 / 29
页数：29
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