Recent Advances of Transition Metal-Catalyzed C(sp3)-C(sp3) Cross-Coupling Reactions of Non-activated Alkyl Halides

被引：15
|
作者：
Zhang, Wenman [1 ]
Dai, Jianjun [1 ]
Xu, Huajian [1 ]
机构：
[1] Hefei Univ Technol, Sch Med Engn, Hefei 230009, Peoples R China
来源：
CHINESE JOURNAL OF ORGANIC CHEMISTRY | 2015年 / 35卷 / 09期
基金：
中国国家自然科学基金; 中国博士后科学基金;
关键词：
transition-metal; catalyze; non-activated alkyl halide; cross-coupling; advance; ALPHA-AMINO-ACIDS; C-H BONDS; GRIGNARD-REAGENTS; SUZUKI REACTIONS; ORGANOBORON COMPOUNDS; BORONIC ACIDS; SECONDARY; BROMIDES; TOSYLATES; ELECTROPHILES;
D O I：
10.6023/cjoc201503007
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Recently, great attention has been directed to the transition-metal-catalyzed cross-coupling reactions of non-activated alkyl halides for the construction of C(sp(3))-C(sp(3)) bonds. However, due to the difficulty of oxidative addition of the non-activated alkyl halides with a metal catalyst and the resulting metal-alkyl intermediate prone to beta-H elimination, the cross-coupling of non-activated alkyl halides with alkyl nucleophiles remains a challenge. This review summarizes the recent advances of C(sp(3))-C(sp(3)) cross-coupling of non-activated alkyl halides catalyzed by transition-metals.
引用
收藏
页码：1820 / 1833
页数：14
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