Carboxylation of terminal alkynes promoted by silver carbamate at ambient pressure

被引：16
|
作者：
Bresciani, Giulio [1 ,2 ]
Marchetti, Fabio [1 ,2 ]
Pampaloni, Guido [1 ,2 ]
机构：
[1] Univ Pisa, Dipartimento Chim & Chim Ind, Via Moruzzi 13, I-56124 Pisa, Italy
[2] CIRCC, Via Celso Ulpiani 27, I-70126 Bari, Italy
来源：
NEW JOURNAL OF CHEMISTRY | 2019年 / 43卷 / 27期
关键词：
CARBON-DIOXIDE; CATALYTIC PRECURSORS; SELECTIVE OXIDATION; CO2; CONVERSION; COMPLEXES; COPPER; POLYMERIZATION; ACTIVATION; FIXATION;
D O I：
10.1039/c9nj02203a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Transition metal carbamates constitute a class of compounds with unique properties, however their catalytic potential has been sparingly explored so far. The easily available silver N,N-dimethylcarbamate, Ag(O2CNMe2), worked as a catalyst in the carboxylation reaction of terminal alkynes with CO2 at atmospheric pressure. Different reaction parameters (solvent, base, temperature, time and the amount of catalyst) were investigated in order to establish the optimal conditions.
引用
收藏
页码：10821 / 10825
页数：5
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