Bicyclo[10.10.10]dotriacontanes:: the largest bicyclo[n.n.n]alkane ever known

被引：7
|
作者：
Kurata, H [1 ]
Rikitake, N [1 ]
Okumura, A [1 ]
Oda, M [1 ]
机构：
[1] Osaka Univ, Grad Sch Sci, Dept Chem, Toyonaka, Osaka 5600043, Japan
来源：
CHEMISTRY LETTERS | 2004年 / 33卷 / 08期
关键词：
D O I：
10.1246/cl.2004.1018
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Bicyclo[10.10.10]dotriacontanes, the largest bicyclo[n.n.n]-alkanes ever known, have been first synthesized by Raney nickel reduction of trithienyltmethanophanes consisiting of two tris(2-thienyl)methanes and three etheno bridges. X-ray crystallographic analysis of a crystalline derivative confirmed the structure, though disorder of included hexane molecules lowered the accuracy.
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收藏
页码：1018 / 1019
页数：2
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