Differential pulse voltammetry on spherical microelectrodes

被引：0
|
作者：
Lovric, M [1 ]
机构：
[1] Rudjer Boskovic Inst, Ctr Marine Res, HR-10001 Zagreb, Croatia
来源：
ELECTROANALYSIS | 1999年 / 11卷 / 15期
关键词：
differential pulse voltammetry; differential pulse polarography; spherical microelectrode;
D O I：
10.1002/(SICI)1521-4109(199911)11:15<1089::AID-ELAN1089>3.3.CO;2-A
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
A theory of differential pulse voltammetry (DPV) and polarography (DPP) of reversible redox reaction on the spherical electrode is developed. Numerical solutions for DPV peak currents and peak potentials are compared with the analytical solutions obtained for DPP and satisfactory agreement is found when the period between pulses is more than five times longer than the pulse. Under this condition the application of the theory is greatly simplified.
引用
收藏
页码：1089 / 1093
页数：5
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